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六水合钴双（2-甲基-1-咪唑-3-鎓）四水合双（苯-1,3,5-三羧酸根-κ）钴的合成与结构

Synthesis and structure of hexa-aqua-cobalt bis-(2-methyl-1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato-κ)cobalt.

作者信息

Velazquez-Garcia Jose de Jesus, Techert Simone

机构信息

Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany.

Institut für Röntgenphysik, Georg-August-Universität Göttingen, Friedrich-Hund-Platz 1, Göttingen, 37077, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 Jul 19;78(Pt 8):814-817. doi: 10.1107/S2056989022007046. eCollection 2022 Aug 1.

DOI:10.1107/S2056989022007046
PMID:35974818
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9361360/
Abstract

The title compound, (CHN)[Co(HO)][Co(CHO)(HO)] (), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri-carb-oxy-lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of is here reported and compared with the parent complex hexa-aqua-cobalt bis-(1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato)cobalt ().

摘要

标题化合物(CHN)[Co(HO)]Co(CHO)(HO)是在环境条件下由氯化钴(II)、1,3,5-苯三甲酸(Hbtc)和2-甲基咪唑(H-2mIm)合成的。本文报道了的结构，并与母体配合物六水合钴双-(1-咪唑-3-鎓)四水合双-(苯-1,3,5-三羧基-ato)钴()进行了比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/6a3bbda7252e/e-78-00814-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/e182f71e29ea/e-78-00814-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/af4004eaf8b3/e-78-00814-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/6a3bbda7252e/e-78-00814-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/e182f71e29ea/e-78-00814-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/af4004eaf8b3/e-78-00814-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90dd/9361360/6a3bbda7252e/e-78-00814-fig3.jpg

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