六水合钴双（2-甲基-1-咪唑-3-鎓）四水合双（苯-1,3,5-三羧酸根-κ）钴的合成与结构
Synthesis and structure of hexa-aqua-cobalt bis-(2-methyl-1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato-κ)cobalt.
作者信息
Velazquez-Garcia Jose de Jesus, Techert Simone
机构信息
Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany.
Institut für Röntgenphysik, Georg-August-Universität Göttingen, Friedrich-Hund-Platz 1, Göttingen, 37077, Germany.
出版信息
Acta Crystallogr E Crystallogr Commun. 2022 Jul 19;78(Pt 8):814-817. doi: 10.1107/S2056989022007046. eCollection 2022 Aug 1.
The title compound, (CHN)[Co(HO)][Co(CHO)(HO)] (), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri-carb-oxy-lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of is here reported and compared with the parent complex hexa-aqua-cobalt bis-(1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato)cobalt ().
标题化合物(CHN)[Co(HO)]Co(CHO)(HO)是在环境条件下由氯化钴(II)、1,3,5-苯三甲酸(Hbtc)和2-甲基咪唑(H-2mIm)合成的。本文报道了的结构，并与母体配合物六水合钴双-(1-咪唑-3-鎓)四水合双-(苯-1,3,5-三羧基-ato)钴()进行了比较。
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