Ismail I, Khalal M A, Huttula M, Jänkälä K, Bizau J-M, Cubaynes D, Hikosaka Y, Bučar K, Žitnik M, Andric L, Lablanquie P, Palaudoux J, Penent F
Sorbonne Université, CNRS, Laboratoire de Chimie Physique-Matière et Rayonnement, LCPMR, F-75005 Paris Cedex 05, France.
Nano and Molecular Systems Research Unit, University of Oulu, PO Box 3000, FI-90014, Finland.
Phys Chem Chem Phys. 2022 Aug 31;24(34):20219-20227. doi: 10.1039/d2cp02930h.
Single-photon multiple photoionization results from electron correlations that make this process possible beyond the independent electron approximation. To study this phenomenon experimentally, the detection in coincidence of all emitted electrons is the most direct approach. It provides the relative contribution of all possible multiple ionization processes, the energy distribution between electrons that can reveal simultaneous or sequential mechanisms, and, if possible, the angular correlations between electrons. In the present work, we present a new magnet design of our magnetic bottle electron spectrometer that allows the detection of multiply charged Xe ions in coincidence with electrons. This new coincidence detection allows more efficient extraction of minor channels that are otherwise masked by random coincidences. The proof of principle is provided for xenon triple ionization.
单光子多光电离源于电子关联,这种关联使得该过程在独立电子近似之外成为可能。为了通过实验研究这一现象,对所有发射电子进行符合探测是最直接的方法。它提供了所有可能的多电离过程的相对贡献、电子之间的能量分布(可揭示同时或相继机制),并且如果可能的话,还能提供电子之间的角关联。在本工作中,我们展示了一种新型磁瓶电子谱仪的磁体设计,该设计允许对多重带电的Xe离子与电子进行符合探测。这种新的符合探测能够更有效地提取那些否则会被随机符合所掩盖的次要通道。针对氙的三重电离给出了原理证明。