Yang Bintong, Fang Jiefeng, Xu Chunyang, Cao Hui, Zhang Ruixuan, Zhao Biao, Huang Mengqiu, Wang Xiangyu, Lv Hualiang, Che Renchao
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai, 200438, People's Republic of China.
Willian G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, Columbus, OH, 43210, USA.
Nanomicro Lett. 2022 Aug 20;14(1):170. doi: 10.1007/s40820-022-00920-7.
Rational designing of one-dimensional (1D) magnetic alloy to facilitate electromagnetic (EM) wave attenuation capability in low-frequency (2-6 GHz) microwave absorption field is highly desired but remains a significant challenge. In this study, a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method. The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique, indicating the excellent magnetic loss ability under an external EM field. Then, the in-depth analysis shows that many factors, including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy, primarily contribute to the enhanced EM wave absorption performance. Therefore, the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm. Thus, this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers.
合理设计一维(1D)磁性合金以增强其在低频(2 - 6 GHz)微波吸收场中的电磁波(EM)衰减能力是非常必要的,但仍然是一项重大挑战。在本研究中,通过改进的静电纺丝方法合理设计了一种由嵌入一维碳基框架中的FeCoNi中熵合金制成的复合电磁波吸收体。使用离轴电子全息技术,一维形状的FeCoNi合金嵌入复合材料展示了高密度和连续的磁网络,表明在外部电磁场下具有优异的磁损耗能力。然后,深入分析表明,包括一维各向异性和磁性中熵合金的固有物理特性在内的许多因素,对增强的电磁波吸收性能起主要作用。因此,所制备的电磁波吸收体在2 mm的超薄厚度下,在低频电磁场中显示出1.3 GHz的有效吸收带宽增加。因此,本研究为高性能一维磁性电磁波吸收体的设计和制备开辟了一种新方法。
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