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用于高效清理粘性油的太阳能辅助超疏水MoS/PDMS/MS海绵

Solar-Assisted Superhydrophobic MoS/PDMS/MS Sponge for the Efficient Cleanup of Viscous Oil.

作者信息

Wu Zhuobin, Zheng Ke, Cheng Zuqin, Zhou Shaoqi

机构信息

School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China.

College of Resource and Environmental Engineering, Guizhou University, Guiyang 550003, P. R. China.

出版信息

Langmuir. 2022 Sep 6;38(35):10902-10914. doi: 10.1021/acs.langmuir.2c01809. Epub 2022 Aug 24.

Abstract

Industrialization releases many high-viscosity oil pollutants into the environment, requiring a hydrophobic recyclable oil-absorbing material. Therefore, a self-heating and superhydrophobic melamine sponge (MS) by connecting polydimethylsiloxane (PDMS) was coated with functionalized molybdenum disulfide (MoS) nanosheets on a three-dimensional microstructure of a commercial MS (MoS/PDMS/MS) via a simple and low-cost dip-coating method. The prepared sponge showed a water contact angle of 151.8°, indicating that the modified sponge exhibited superhydrophobicity. Due to the addition of MoS, the modified sponge can convert light into heat, and its surface could be heated to 59.7 °C within 30 s. Because of the excellent MoS/PDMS/MS photothermal performance, the sponge could decrease the viscosity of the high-viscosity oil, absorbing the high-viscosity oil efficiently. After simultaneous thermal analysis and repeated compression tests, the modified sponge exhibited high thermochemical stability, mechanical property, and reusability. This superhydrophobic multifunctional sponge shows excellent potential for high-viscosity oil absorption.

摘要

工业化向环境中释放了许多高粘度油污染物,这就需要一种疏水可回收的吸油材料。因此,通过连接聚二甲基硅氧烷(PDMS)制备了一种自热超疏水三聚氰胺海绵(MS),并通过简单且低成本的浸涂方法在商用MS的三维微观结构上涂覆了功能化二硫化钼(MoS)纳米片(MoS/PDMS/MS)。制备的海绵水接触角为151.8°,表明改性海绵具有超疏水性。由于添加了MoS,改性海绵能够将光转化为热,其表面在30秒内可加热至59.7°C。由于MoS/PDMS/MS具有优异的光热性能,该海绵能够降低高粘度油的粘度,高效吸收高粘度油。经过同步热分析和反复压缩测试,改性海绵表现出高热化学稳定性、机械性能和可重复使用性。这种超疏水多功能海绵在高粘度油吸收方面显示出优异的潜力。

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