文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期,新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

用于高效水-油乳液分离及快速太阳能辅助高粘度原油吸附与回收的超疏水聚氨酯海绵

Superhydrophobic polyurethane sponge for efficient water-oil emulsion separation and rapid solar-assisted highly viscous crude oil adsorption and recovery.

作者信息

Chen Jiajun, Sun Ming, Ni Yimeng, Zhu Tianxue, Huang Jianying, Li Xiao, Lai Yuekun

机构信息

College of Chemical Engineering, Fuzhou University, Fuzhou 350116, PR China.

Qingyuan Innovation Laboratory, Quanzhou 362801, PR China.

出版信息

J Hazard Mater. 2023 Mar 5;445:130541. doi: 10.1016/j.jhazmat.2022.130541. Epub 2022 Dec 5.


DOI:10.1016/j.jhazmat.2022.130541
PMID:36493650
Abstract

Rapid and efficient cleaning of oily wastewater and high viscosity crude oil spills is still a global challenge. Conventional three-dimensional porous adsorbents are ineffective for oil-water separation in harsh environment and are restricted to the low fluidity of high viscosity crude oil at room temperature. Increasing temperature can enormously improve the fluidity of viscous crude oil. Herein, the polydimethylsiloxane (PDMS) /carbon black (CB) -modified polyurethane sponge (PU) were prepared by a simple one-step dip-coating method. PDMS/CB@PU (PCPU) exhibits high adsorption capacity to various oils and organic liquid (28.5-68.7 g/g), strong mechanical properties (500 cycles at 50%), outstanding reusability (100 cycles of adsorption and desorption) and excellent environmental stability due to the special PDMS/CB coating. The maximum surface temperature of PCPU sponge can reach 84.7 ℃ under 1 sunlight irradiation. Therefore, the PCPU sponge can rapidly heat and enhance the fluidity of viscous crude oil, significantly speeding up the viscous oil recovery process with the maximum adsorption capacity of 44.7 g/g. In addition, the PCPU sponge can also combine with the vacuum pump to realize the continuous and rapid repair of viscous oil spills from the seawater surface. In consideration of its simple preparation, cost-effectiveness and high oil absorption ability, this solar-assisted self-heating adsorbent provides a new direction for large-scale cleanup and recycling of viscous crude oil spill on the seawater surface.

摘要

快速高效地清理含油废水和高粘度原油泄漏仍然是一项全球性挑战。传统的三维多孔吸附剂在恶劣环境下对油水分离无效,并且受限于室温下高粘度原油的低流动性。升高温度可以极大地提高粘性原油的流动性。在此,通过简单的一步浸涂法制备了聚二甲基硅氧烷(PDMS)/炭黑(CB)改性的聚氨酯海绵(PU)。由于特殊的PDMS/CB涂层,PDMS/CB@PU(PCPU)对各种油类和有机液体表现出高吸附容量(28.5 - 68.7 g/g)、强机械性能(50%应变下500次循环)、出色的可重复使用性(100次吸附-解吸循环)以及优异的环境稳定性。在1倍太阳光照射下,PCPU海绵的最高表面温度可达84.7℃。因此,PCPU海绵能够快速加热并提高粘性原油的流动性,显著加速粘性油回收过程,最大吸附容量为44.7 g/g。此外,PCPU海绵还可与真空泵结合,实现从海水表面连续快速修复粘性油泄漏。考虑到其制备简单、成本效益高和吸油能力强,这种太阳能辅助自热吸附剂为大规模清理和回收海水表面粘性原油泄漏提供了新方向。

相似文献

[1]
Superhydrophobic polyurethane sponge for efficient water-oil emulsion separation and rapid solar-assisted highly viscous crude oil adsorption and recovery.

J Hazard Mater. 2023-3-5

[2]
Coupling Carbon-Based Composite Phase Change Materials with a Polyurethane Sponge for Sustained and Efficient Solar-Driven Cleanup of Viscous Crude Oil Spill.

ACS Appl Mater Interfaces. 2023-8-9

[3]
Thermally Conductive and Superhydrophobic Polyurethane Sponge for Solar-Assisted Separation of High-Viscosity Crude Oil from Water.

ACS Appl Mater Interfaces. 2022-2-9

[4]
Solar-assisted high-efficient cleanup of viscous crude oil spill using an ink-modified plant fiber sponge.

J Hazard Mater. 2022-6-15

[5]
Multifunctional magnetic sponge with outstanding solar/electro-thermal performance for high-efficiency and all-day continuous cleanup of crude oil spills.

Sci Total Environ. 2023-9-20

[6]
A sponge heated by electromagnetic induction and solar energy for quick, efficient, and safe cleanup of high-viscosity crude oil spills.

J Hazard Mater. 2022-8-15

[7]
Robust mussel-inspired superhydrophobic sponge with eco-friendly photothermal effect for crude oil/seawater separation.

J Hazard Mater. 2024-1-5

[8]
Solar-Assisted, Fast, and Recovery of Crude Oil Spill by a Superhydrophobic and Photothermal Sponge.

ACS Appl Mater Interfaces. 2021-5-12

[9]
Solar-assisted isotropically thermoconductive sponge for highly viscous crude oil spill remediation.

iScience. 2021-5-29

[10]
Photothermal and Joule heating-assisted thermal management sponge for efficient cleanup of highly viscous crude oil.

J Hazard Mater. 2021-2-5

引用本文的文献

[1]
Research Progress on Oil-Water Separation Materials Based on Polyurethane Modification.

ACS Omega. 2024-12-25

[2]
Hydrophobic dual-polymer-reinforced graphene composite aerogel for efficient water-oil separation.

RSC Adv. 2025-1-3

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索