Laser Ablation on Isostatic Graphite-A New Way to Create Exfoliated Graphite.

In search of a new way to fabricate graphene-like materials, isostatic graphite targets were ablated using high peak power with a nanosecond-pulsed infrared laser. We conducted dry ablations in an argon atmosphere and liquid-phase ablations in the presence of a liquid medium (water or toluene). After the dry ablation, the SEM images of the target showed carbon in the form of a volcano-like grain structure, which seemed to be the result of liquid carbon ejected from the ablation center. No graphite exfoliation could be achieved using dry ablation. When using liquid phase ablation with water or toluene as a liquid medium, no traces of the formation of liquid carbon were found, but cleaner and deeper craters were observed. In particular, when using toluene as a liquid medium, typical graphite exfoliation was found. We believe that due to the extremely high pressure and high temperature induced by the laser pulses, toluene was able to intercalate into the graphite layers. Between the laser pulses, the intercalated toluene was able to flash evaporate and blow-up the graphite, which resulted in exfoliated graphite. Exfoliated graphite was found on the ablated graphite surface, as well as in the toluene medium. The ablation experiments with toluene undertaken in this study demonstrated an effective method of producing micrometer-sized graphene material. When using water as a liquid medium, no massive graphite exfoliation was observed. This meant that under the used laser conditions, toluene was a better intercalant for graphite exfoliation than water.