Hrčka Richard, Kučerová Viera, Hönig Vladimír
Department of Wood Sciences, Faculty of Wood Sciences and Technology, Technical University in Zvolen, T.G. Masaryka 24, 96001 Zvolen, Slovakia.
Department of Chemistry and Chemical Technologies, Faculty of Wood Sciences and Technology, Technical University in Zvolen, T.G. Masaryka 24, 96001 Zvolen, Slovakia.
Polymers (Basel). 2022 Aug 19;14(16):3400. doi: 10.3390/polym14163400.
Wood stock in a warehouse is a necessary precondition for reliable manufacturing. However, wood can degrade and lose the matter during storage. "Dry-matter loss (DML)" is used to quantify the degradation following the changes in mass of a wood substance. The proposed calculation of DML is based on using parallel figures. The calculated loss of spruce wood substance harvested in winter during a six-month period was 4.5%. The estimated annual loss of wood substance was 5.7%. The loss was caused by a factor with a gradually eliminated effect. The changes in the chemical composition of wood substance were not proportional to the original amount of the isolated chemical substances. Hemicelluloses and lignin suffered from the loss faster than there was a change in the DML of spruce wood. Hemicelluloses were the most unstable isolated compound, with an increased rate of change during the first four months. The number of extractives significantly decreased during two months of storage. However, there was an increase in the number of extractives after six months of storage. The loss of cellulose was similar to the DML of spruce wood during the whole time of storage. The FTIR analysis confirmed a decrease in the total crystalline index (TCI) and lateral order index (LOI) of cellulose due to the storage of roundwood.
仓库中的木材储备是可靠生产的必要前提条件。然而,木材在储存过程中会降解并失重。“干物质损失(DML)”用于量化木材物质质量变化后的降解情况。提议的DML计算基于使用平行数据。冬季采伐的云杉木在六个月期间计算得出的木材物质损失为4.5%。估计的木材物质年损失为5.7%。这种损失是由一种具有逐渐消除效应的因素造成的。木材物质的化学成分变化与分离出的化学物质的原始量不成比例。半纤维素和木质素比云杉木的DML变化更快地遭受损失。半纤维素是最不稳定的分离化合物,在前四个月变化率增加。在储存的两个月中,提取物的数量显著减少。然而,在储存六个月后,提取物的数量有所增加。在整个储存期间,纤维素的损失与云杉木的DML相似。傅里叶变换红外光谱(FTIR)分析证实,由于原木储存,纤维素的总结晶指数(TCI)和侧向有序指数(LOI)降低。