Salih Shameran Jamal, Abdul Kareem Aram Salahuddin, Anwer Sewgil Saaduldeen
Department of Chemistry, Faculty of Science and Health, Koya University, Koya KOY45, Kurdistan Region - F.R. Iraq.
Department Medical Lab. Science, Lebanese French University, Kurdistan Region, Iraq.
Heliyon. 2022 Aug 11;8(8):e10092. doi: 10.1016/j.heliyon.2022.e10092. eCollection 2022 Aug.
Toxic dyes are irrefutable effluent components of textile wastewater, so they have become a major economic and health concern. With the purpose of efficient removal of textile dyes, multiple nature-inspired adsorbents have been applied. Herein, raw corncob is proposed as a novel highly efficient, low-price, and abundantly attainable adsorbent with the potential for uptake of methyl red and methyl orange. Multiple experiments were carried out to optimize parameters including pH, primary concentration, adsorbent dosage, temperature, and contact time. The adsorption was raised with the mounting of the contact time and it was alleviated with the addition of initial concentration. The foremost uptake of dye was apperceived at an acidic medium pH 4 for methyl red and pH 1 for methyl orange. Scanning Electron Microscopy and Fourier Transform Infrared Spectroscopy were employed to characterize the surfaces of corncobs. The well-fitted Langmuir and Freundlich models (methyl red: R = 0.9956 and methyl orange: R = 0.9883) confirmed the homogeneous monolayer adsorption process on the raw corncob surface. The obtained results disclose that corncob is an effectual biosorbent for eliminating anionic dyes without the necessity for any prior modifications.
有毒染料是纺织废水不可忽视的排放成分,因此已成为主要的经济和健康问题。为了高效去除纺织染料,人们应用了多种仿生吸附剂。在此,提出将生玉米芯作为一种新型的高效、低价且易于获取的吸附剂,它具有吸附甲基红和甲基橙的潜力。进行了多项实验以优化包括pH值、初始浓度、吸附剂用量、温度和接触时间等参数。吸附量随着接触时间的增加而提高,随着初始浓度的增加而降低。对于甲基红,在酸性介质pH值为4时观察到最大染料吸附量;对于甲基橙,在pH值为1时观察到最大染料吸附量。采用扫描电子显微镜和傅里叶变换红外光谱对玉米芯表面进行表征。拟合良好的朗缪尔和弗伦德利希模型(甲基红:R = 0.9956,甲基橙:R = 0.9883)证实了在生玉米芯表面的均匀单层吸附过程。所得结果表明,玉米芯是一种无需任何预先改性即可有效去除阴离子染料的生物吸附剂。