Novel diaminoguanidine functionalized cellulose: synthesis, characterization, adsorption characteristics and application for ICP-AES determination of copper(II), mercury(II), lead(II) and cadmium(II) from aqueous solutions.

In this study, the novel adsorbent diaminoguanidine-modified cellulose (DiGu.MC) was synthesized to extract mercury, copper, lead and cadmium ions from aqueous solutions and environmental water samples. The synthetic strategy involved oxidizing cellulose powder into dialdehyde cellulose (DAC) and reacting DAC with diaminoguanidine to create an imine linkage between the two reactants to form diaminoguanidine-modified cellulose (DiGu.MC). The structure and morphology of the adsorbent were studied using a variety of analytical techniques including Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) surface area measurements. Adsorption of mercury, copper, lead, and cadmium ions was optimized by examining the effects of pH, initial concentration, contact time, dose, temperature and competing ions. Under optimal adsorption conditions, the adsorption capacities of Cu, Hg, Pb, and Cd were 66, 55, 70 and 41 mg g, respectively. The adsorption isotherm is in very good agreement with the Langmuir isotherm model, indicating that a monomolecular layer is formed on the surface of DiGu.MC. The kinetics of adsorption are in good agreement with the pseudo-second kinetics model that proposes the chemical adsorption of metal ions via the nitrogen functional groups of the adsorbent. Thermodynamic studies have confirmed that the adsorption of heavy metals by DiGu.MC is exothermic and spontaneous. Regeneration studies have shown that the adsorbent can be recycled multiple times by removing metal ions with 0.2 M nitric acid. The removal efficiency for regeneration was over 99%. DiGu.MC is introduced as a unique adsorbent in removing mercury, copper, lead and cadmium with a simple synthetic strategy, with cheap starting materials, a unique chemical structure and fast adsorption kinetics leading to excellent removal efficiency and excellent regeneration. The mechanism of adsorption of the investigated heavy metals, is probably based on the chelation between the metal ions and the N donors of DiCu.MC.