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采用电化学方法制备的CeO/rGO纳米带修饰的FTO电极测定水中重金属。

Determination of heavy metals in water using an FTO electrode modified with CeO/rGO nanoribbons prepared by an electrochemical method.

作者信息

Zhao Nan, Ren Lu, Du Guangyi, Liu Jing, You Xueqiu

机构信息

School of Ocean Information Engineering, Jimei University Xiamen 361021 China

Northwest Engineering Corporation Limited, PowerChina Xi'an 710065 China.

出版信息

RSC Adv. 2022 Aug 8;12(34):21851-21858. doi: 10.1039/d2ra03153a. eCollection 2022 Aug 4.

Abstract

The rGO/CeO/FTO nanocomposite modified electrode was prepared by an electrochemical method. A simple and highly sensitive electrochemical sensing platform for electrochemical rGO and modified CeO nanoribbons directly on FTO electrodes was developed. Simultaneous determination of Pb and Cd used the differential pulse anodic stripping voltammetry (DPASV) method. The method was simple to operate, and CeO nanobelts could be obtained simultaneously by electrodeposition and reduction of GO without further processing. This is an environmentally friendly electrochemical method to obtain modified electrodes under mild conditions. The experimental results showed that the linear calibration curves of Pb and Cd are 1-300 and 0.2-500 μg L, respectively. At the same time, no interference from other coexisting metal ions was found during the detection process, which proved that the modified electrode had good stability and repeatability.

摘要

通过电化学方法制备了rGO/CeO/FTO纳米复合修饰电极。开发了一种简单且高灵敏度的电化学传感平台,用于在FTO电极上直接对电化学还原氧化石墨烯(rGO)和修饰的CeO纳米带进行检测。采用差分脉冲阳极溶出伏安法(DPASV)同时测定Pb和Cd。该方法操作简单,通过电沉积和氧化石墨烯(GO)的还原可同时获得CeO纳米带,无需进一步处理。这是一种在温和条件下获得修饰电极的环境友好型电化学方法。实验结果表明,Pb和Cd的线性校准曲线分别为1 - 300和0.2 - 500 μg L。同时,检测过程中未发现其他共存金属离子的干扰,这证明修饰电极具有良好的稳定性和重复性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b7/9358772/bc39eac6d5dc/d2ra03153a-f1.jpg

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