Synergism between iron porphyrin and dicationic ionic liquids: tandem CO electroreduction-carbonylation reactions.
作者信息
Miró Roger, Fernández-Llamazares Emma, Godard Cyril, Díaz de Los Bernardos Miriam, Gual Aitor
机构信息
Fundació EURECAT, Unitat de Tecnologia Química, C/Marceli Domingo 2, 43007 Tarragona, Spain.
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marceli Domingo 1, 43007 Tarragona, Spain.
出版信息
Chem Commun (Camb). 2022 Sep 20;58(75):10552-10555. doi: 10.1039/d2cc03641j.
Here, we report a simple procedure that drastically reduces the electrochemical (Fe/Fe) and 0cat of the commercially available iron(III) tetraphenylporphyrin chloride (FeTPP·Cl) catalyst via a synergetic effect with the imidazolium dications of the ionic liquid electrolyte. This procedure enhanced the performance of catalytic systems in the electrochemical production of CO and enabled us to perform different tandem CO reduction-carbonylation reactions under mild conditions.
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