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最大化半透明钙钛矿太阳能电池性能的关键途径:光子传播管理与载流子动力学调控

Pivotal Routes for Maximizing Semitransparent Perovskite Solar Cell Performance: Photon Propagation Management and Carrier Kinetics Regulation.

作者信息

Wu Hangjuan, Cheng Yajie, Ma Junjie, Zhang Jiahao, Zhang Yiqiang, Song Yanlin, Peng Shou

机构信息

School of Materials Science and Engineering, College of Chemistry, Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou, 450001, P. R. China.

Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.

出版信息

Adv Mater. 2023 Feb;35(5):e2206574. doi: 10.1002/adma.202206574. Epub 2022 Dec 5.

Abstract

Semitransparent perovskite solar cells (ST-PSCs) are ideal candidates for building-integrated photovoltaics (BIPV) and tandem solar cells (TSCs) owing to their tunable bandgap and high visible transparency. The best power conversion efficiency (PCE) of ST-PSCs is close to 15% with an average visible transmittance of over 20%, which still lags far behind the PCE of normal opaque PSCs. This can be attributed to the poor light utilization efficiency (LUE) of ST-PSCs. Herein, the pivotal routes for maximizing LUE of ST-PSCs in terms of photon propagation management and carrier kinetics regulation are systematically rationalized. First, the fundamental theoretical analyses on optical processes and electronic properties are provided. Then, insights on photon propagation management measures and carrier kinetics regulation strategies are provided. Furthermore, a summary of the promising commercial application of ST-PSCs in BIPV and TSCs is provided. Finally, the main progress of ST-PSCs is briefly summarized, and the directions for the commercialization of ST-PSCs are proposed.

摘要

半透明钙钛矿太阳能电池(ST-PSC)因其可调带隙和高可见光透明度,是建筑一体化光伏(BIPV)和串联太阳能电池(TSC)的理想选择。ST-PSC的最佳功率转换效率(PCE)接近15%,平均可见光透过率超过20%,但仍远远落后于普通不透明PSC的PCE。这可归因于ST-PSC的光利用效率(LUE)较差。在此,从光子传播管理和载流子动力学调控方面,系统地阐述了最大化ST-PSC的LUE的关键途径。首先,提供了关于光学过程和电子性质的基础理论分析。然后,给出了光子传播管理措施和载流子动力学调控策略的见解。此外,还总结了ST-PSC在BIPV和TSC中的商业应用前景。最后,简要总结了ST-PSC的主要进展,并提出了ST-PSC商业化的方向。

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