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通过粉末冶金法制备的用于生物医学应用的Ti64/20Ag多孔复合材料

Ti64/20Ag Porous Composites Fabricated by Powder Metallurgy for Biomedical Applications.

作者信息

Olmos Luis, Gonzaléz-Pedraza Ana S, Vergara-Hernández Héctor J, Chávez Jorge, Jimenez Omar, Mihalcea Elena, Arteaga Dante, Ruiz-Mondragón José J

机构信息

INICIT, Universidad Michoacana de San Nicolás de Hidalgo, Fco. J. Mujica S/N, Morelia C.P. 58060, Mexico.

División de Estudios de Posgrado e Investigación, Tecnológico Nacional de México/I.T. Morelia, Av. Tecnológico #1500, Colonia Lomas de Santiaguito, Morelia C.P. 58120, Mexico.

出版信息

Materials (Basel). 2022 Aug 29;15(17):5956. doi: 10.3390/ma15175956.

Abstract

We present a novel Ti64/20Ag highly porous composite fabricated by powder metallurgy for biomedical applications and provide an insight into its microstructure and mechanical proprieties. In this work, the Ti64/20Ag highly porous composites were successfully fabricated by the space holder technique and consolidated by liquid phase sintering, at lower temperatures than the ones used for Ti64 materials. The sintering densification was evaluated by dilatometry tests and the microstructural characterization and porosity features were determined by scanning electron microscopy and computed microtomography. Permeability was estimated by numerical simulations on the 3D real microstructure. Mechanical properties were evaluated by simple compression tests. Densification was achieved by interparticle pore filling with liquid Ag that does not drain to the large pores, with additional densification due to the macroscopical deformation of large pores. Pore characteristics are closely linked to the pore formers and the permeability was highly increased by increasing the pore volume fraction, mainly because the connectivity was improved. As expected, with the increase in porosity, the mechanical properties decreased. These results permitted us to gain a greater understanding of the microstructure and to confirm that we developed a promising Ti64/20Ag composite, showing E of 7.4 GPa, σ of 123 MPa and permeability of 3.93 × 10 m. Enhanced adaptability and antibacterial proprieties due to Ag were obtained for bone implant applications.

摘要

我们展示了一种通过粉末冶金法制造的用于生物医学应用的新型Ti64/20Ag高孔隙率复合材料,并深入研究了其微观结构和力学性能。在这项工作中,采用空间保持技术成功制备了Ti64/20Ag高孔隙率复合材料,并通过液相烧结进行固结,烧结温度低于用于Ti64材料的温度。通过膨胀计测试评估烧结致密化,并通过扫描电子显微镜和计算机显微断层扫描确定微观结构特征和孔隙率特征。通过对三维真实微观结构的数值模拟估算渗透率。通过简单的压缩试验评估力学性能。通过液态Ag填充颗粒间孔隙实现致密化,液态Ag不会排入大孔隙,大孔隙的宏观变形导致额外的致密化。孔隙特征与成孔剂密切相关,通过增加孔隙体积分数可显著提高渗透率,主要是因为连通性得到改善。正如预期的那样,随着孔隙率的增加,力学性能下降。这些结果使我们对微观结构有了更深入的了解,并证实我们开发了一种有前景的Ti64/20Ag复合材料,其弹性模量为7.4 GPa,屈服强度为123 MPa,渗透率为3.93×10 m。由于Ag,该复合材料在骨植入应用中具有增强的适应性和抗菌性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6035/9457260/e53205de9d1b/materials-15-05956-g001.jpg

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