Moreira Bruno Rafael de Almeida, Cruz Victor Hugo, Barbosa Júnior Marcelo Rodrigues, Meneses Mariana Dias, Lopes Paulo Renato Matos, da Silva Rouverson Pereira
Department of Engineering and Mathematical Sciences, School of Agricultural and Veterinary Sciences, São Paulo State University (Unesp), Jaboticabal, São Paulo Brazil.
Department of Plant Production, School of Agricultural and Technological Sciences, São Paulo State University (Unesp), Dracena, São Paulo Brazil.
Biomass Convers Biorefin. 2022 Sep 15:1-22. doi: 10.1007/s13399-022-03285-4.
Incineration and landfilling offer possibilities for addressing high-rate management of COVID-waste streams. However, they can be costly and environmentally unsustainable. In addition, they do not allow to convert them to fuels and chemicals as waste-to-energy and waste-to-product technologies. Therefore, we analyzed whether integrating hydrothermal carbonization (HTC) and pelletization can allow converting the surgical face mask (SFM) and biomass to composite plastic-fiber fuel (CPFF). We blended the plastic material and corncob, peanut shell, or sugarcane bagasse at the proportion of 50:50 (%, dry mass basis) for HTC. We performed the thermal pretreatment of blends in an autoclaving reactor at 180 °C and 1.5 MPa. Then we pelletized the hydrochars in a presser machine at 200 MPa and 125 °C. By analyzing the evidence from our study, we recognized the viability of combining the SFM and agricultural residues for CPFF from comparable technical features of our products to standards for premium-grade wood pellets. For instance, the elemental composition of their low-meltable ash was not stoichiometrically sufficient to severely produce slagging and fouling in the equipment for thermal conversion. Although they contained synthetic polymers in their structures, such as polyethylene from filter layers and nylon from the earloop, they emitted CO and NO below the critical limits of 200 and 500 mg m, respectively, for occupational safety. Therefore, we extended the knowledge on waste-to-energy pathways to transform SFM into high-quality hybrid fuel by carbonization and pelletization. Our framework can provide stakeholders opportunities to address plastic and biogenic waste in the context of a circular economy.
The online version contains supplementary material available at 10.1007/s13399-022-03285-4.
焚烧和填埋为解决新冠疫情产生的大量废弃物管理问题提供了可能。然而,它们成本高昂且在环境方面不可持续。此外,与废物转化为能源和废物转化为产品的技术不同,它们无法将这些废弃物转化为燃料和化学品。因此,我们分析了将水热碳化(HTC)和造粒相结合是否能够将医用口罩(SFM)和生物质转化为复合塑料纤维燃料(CPFF)。我们将塑料材料与玉米芯、花生壳或甘蔗渣按50:50(质量百分比,干基)的比例混合用于水热碳化。我们在高压釜式反应器中于180°C和1.5MPa的条件下对混合物进行热预处理。然后在压力机中于200MPa和125°C的条件下将水热炭制成颗粒。通过分析我们研究中的证据,从我们产品与优质木颗粒标准的可比技术特征来看,我们认识到将SFM和农业残留物结合用于CPFF的可行性。例如,其低熔点灰分的元素组成在化学计量上不足以在热转换设备中严重产生结渣和积垢。尽管它们的结构中含有合成聚合物,如过滤层中的聚乙烯和耳挂中的尼龙,但就职业安全而言,它们排放的一氧化碳和一氧化氮分别低于200和500mg/m的临界限值。因此,我们拓展了关于废物转化为能源途径的知识,通过碳化和造粒将SFM转化为高质量的混合燃料。我们的框架可为利益相关者提供在循环经济背景下处理塑料和生物源废物的机会。
在线版本包含可在10.1007/s13399 - 022 - 03285 - 4获取的补充材料。