铜（I）催化伯胺与2,2'-二溴-1,1'-联苯的交叉偶联反应用于合成多取代咔唑。
Cu(i)-catalyzed cross-coupling of primary amines with 2,2'-dibromo-1,1'-biphenyl for the synthesis of polysubstituted carbazole.
作者信息
Niu Yan-Ning, Qiao Yan, Wang Ke-Yu, Sha Bai-Xue, Li Gao-Qiang
机构信息
Department of Teaching and Research, Nanjing Forestry University Huaian Jiangsu 223003 People's Republic of China
Key Laboratory of Macromolecular Science of Shanxi Province, School of Chemistry and Chemical Engineering, Shanxi Normal University Xi'an Shanxi 710062 People's Republic of China.
出版信息
RSC Adv. 2022 Aug 25;12(37):24232-24236. doi: 10.1039/d2ra03323b. eCollection 2022 Aug 22.
A Cu(i)-catalyzed cross-coupling of primary amines with 2,2'-dibromo-1,1'-biphenyl for the synthesis of polysubstituted carbazole has been achieved. This protocol provides an efficient strategy for the synthesis of carbazole using cheap copper catalysts with diamine ligand, and it provides convenient access to a series of carbazole derivatives in moderate yields.
实现了一种铜（I）催化的伯胺与2,2'-二溴-1,1'-联苯的交叉偶联反应，用于合成多取代咔唑。该方法为使用廉价的铜催化剂和二胺配体合成咔唑提供了一种有效策略，并且能够以中等产率方便地获得一系列咔唑衍生物。
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