Bender Philipp, Marcano Lourdes, Orue Iñaki, Alba Venero Diego, Honecker Dirk, Fernández Barquín Luis, Muela Alicia, Fdez-Gubieda M Luisa
Department of Physics and Materials Science, University of Luxembourg 1511 Luxembourg Grand Duchy of Luxembourg
Helmholtz-Zentrum Berlin für Materialien und Energie 12489 Berlin Germany.
Nanoscale Adv. 2020 Feb 27;2(3):1115-1121. doi: 10.1039/c9na00434c. eCollection 2020 Mar 17.
biosynthesize high-quality magnetite nanoparticles, called magnetosomes, and arrange them into a chain that behaves like a magnetic compass. Here we perform magnetometry and polarized small-angle neutron scattering (SANS) experiments on a powder of freeze-dried and immobilized . We confirm that the individual magnetosomes are single-domain nanoparticles and that an alignment of the particle moments along the magnetic field direction occurs exclusively by an internal, coherent rotation. Our magnetometry results of the bacteria powder indicate an absence of dipolar interactions between the particle chains and a dominant uniaxial magnetic anisotropy. Finally, we can verify by SANS that the chain structure within the immobilized, freeze-dried bacteria is preserved also after application of large magnetic fields up to 1 T.
生物合成高质量的磁铁矿纳米颗粒,即磁小体,并将它们排列成一条类似磁罗盘的链。在这里,我们对冻干和固定化的粉末进行了磁力测量和极化小角中子散射(SANS)实验。我们证实,单个磁小体是单畴纳米颗粒,并且颗粒磁矩沿磁场方向的排列完全通过内部的相干旋转发生。我们对细菌粉末的磁力测量结果表明,颗粒链之间不存在偶极相互作用,并且存在占主导地位的单轴磁各向异性。最后,我们可以通过SANS验证,在施加高达1 T的强磁场后,固定化冻干细菌内的链结构也得以保留。
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