Lu Yiming, Fan Xuejia, Ma Xikui, Liu Jian, Li Yangyang, Zhao Mingwen
School of Physics, Shandong University Jinan Shandong 250100 China
Nanoscale Adv. 2022 Apr 6;4(9):2201-2207. doi: 10.1039/d2na00132b. eCollection 2022 May 3.
The rich and exotic electronic properties of graphene nanomeshes (GNMs) have been attracting interest due to their superiority to pristine graphene. Using first-principles calculations, we considered three graphene meshes doped with nitrogen and oxygen atoms (CN, CN and CO). The electronic band structures of these GNMs in terms of the proximity of the Fermi level featured a two-dimensional (2D) honeycomb-kagome lattice with concurrent kagome and Dirac bands. The position of the Fermi level can be regulated by the doping ratio, resulting in different topological quantum states, namely topological Dirac semimetals and Dirac nodal line (DNL) semimetals. More interestingly, the adsorption of rhenium (Re) atoms in the voids of the CN (Re@ CN) GNMs induced quantum anomalous Hall (QAH) states, as verified by the nonzero Chern numbers and chiral edge states. These GNMs offer a promising platform superior to pristine graphene for regulating multiple topological states.
石墨烯纳米网(GNMs)丰富而奇特的电子特性因其相对于原始石墨烯的优越性而备受关注。通过第一性原理计算,我们考虑了三种掺杂有氮和氧原子的石墨烯网(CN、CN和CO)。这些GNMs的电子能带结构在费米能级附近呈现出二维(2D)蜂窝 - Kagome晶格,同时具有Kagome带和狄拉克带。费米能级的位置可以通过掺杂比例来调节,从而产生不同的拓扑量子态,即拓扑狄拉克半金属和狄拉克节线(DNL)半金属。更有趣的是,铼(Re)原子在CN(Re@CN)GNMs的空隙中的吸附诱导了量子反常霍尔(QAH)态,非零的陈数和手性边缘态证实了这一点。这些GNMs为调控多种拓扑态提供了一个优于原始石墨烯的有前景的平台。