Obuseng Veronica C, Moshoeshoe Mohau N, Nareetsile Florence M, Kwaambwa Habauka, Maina Irene
Department of Chemistry, University of Botswana, Gaborone, Botswana.
National University of Lesotho, Roma, Lesotho.
Front Chem. 2022 Sep 7;10:806772. doi: 10.3389/fchem.2022.806772. eCollection 2022.
The world's population is growing continually and is projected to reach nine billion by the year 2050. This growth rate requires increased and economically viable food production and an adequate supply of quality water to sustain life. Increased food production and supply of water require adding fertilizers and possible recycling of wastewater, to address the improvement of soils' nutritional status and potable water shortages, respectively. The objectives of this work were to determine the nutrients in sewage-impacted wastewater, borehole water, agricultural waste, and commercial fertilizer (control) materials, and their heavy metal content was also carried out to determine their suitability for use. In addition, Moringa seed pods and Morula nutshells were investigated as a bioremedial approach for the removal of toxic metals from aqueous samples. An attempt to regenerate sorbent was made since the saturated sorbents that contain the metal ions are not safe for disposal as they can pollute the environment. Nutrients were analyzed by HPLC, while metals were analyzed using a Varian 220FS Atomic Absorption Spectrometer operated with air/acetylene. Nonedible agricultural materials were found to contain appreciable amounts of plant nutrients such as nitrates (NO ), nitrites (NO ), and phosphates (PO ) as well as metal ions such as magnesium, copper, and zinc, which are beneficial for plant growth. Results obtained from analysis of sewage water effluent showed that heavy metal and nutrient concentrations decreased in the treatment stage. The utilization of seed pods for metal removal from wastewater is viable and would reduce costs for waste disposal and can offer alternatives to conventional methods for the removal of unwanted or toxic species from the environment. It showed potential for removing selected metal ions such as Pb, Cd, Cu, Fe, and Zn from polluted water. This organically treated wastewater is environmentally friendly and may be used for applications which do not require potable water, such as irrigating golf courses, lawns, and crops, or for industrial purposes, if proper measures are taken to ensure its quality.
世界人口持续增长,预计到2050年将达到90亿。这种增长速度要求增加粮食产量并使其在经济上可行,同时要有充足的优质水供应以维持生命。增加粮食产量和水供应需要添加肥料并可能对废水进行循环利用,分别解决土壤营养状况改善和饮用水短缺问题。这项工作的目的是测定受污水影响的废水、井水、农业废弃物和商业肥料(对照)材料中的养分,还测定了它们的重金属含量以确定其适用性。此外,研究了辣木种子荚和桑椹果壳作为从水样中去除有毒金属的生物修复方法。由于含有金属离子的饱和吸附剂处置不安全,因为它们会污染环境,所以尝试对吸附剂进行再生。养分通过高效液相色谱法分析,金属使用配备空气/乙炔的瓦里安220FS原子吸收光谱仪进行分析。发现不可食用的农业材料含有大量植物养分,如硝酸盐(NO )、亚硝酸盐(NO )和磷酸盐(PO )以及金属离子,如镁、铜和锌,这些对植物生长有益。对污水排放物的分析结果表明,在处理阶段重金属和养分浓度降低。利用种子荚从废水中去除金属是可行的,这将降低废物处理成本,并可为从环境中去除不需要的或有毒物质的传统方法提供替代方案。它显示出从污染水中去除选定金属离子如铅、镉、铜、铁和锌的潜力。如果采取适当措施确保其质量,这种经过有机处理的废水对环境友好,可用于不需要饮用水的应用,如灌溉高尔夫球场、草坪和作物,或用于工业目的。