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浸没式膜/吸附混合工艺在水回用和浓缩液管理中的应用——小型综述。

Submerged membrane/adsorption hybrid process in water reclamation and concentrate management-a mini review.

机构信息

Faculty of Engineering, University of Technology Sydney (UTS), P.O. Box 123, Broadway, NSW, 2127, Australia.

Faculty of Sciences & Technology (RealTek), Norwegian University of Life Sciences, P.O. Box N-1432, Ås, Norway.

出版信息

Environ Sci Pollut Res Int. 2023 Mar;30(15):42738-42752. doi: 10.1007/s11356-022-23229-9. Epub 2022 Sep 27.

Abstract

Clean water shortage is a major global problem due to escalating demand resulting from increasing human population growth and industrial activities, decreasing freshwater resources and persistent droughts. Recycling and reuse of wastewater by adopting efficient reclamation techniques can help solve this problem. However, wastewater contains a wide range of pollutants, which require removal before it may be reused. Adsorption and membrane processes are two successful treatments used to remove most of these pollutants. Their efficiency increases when these processes are integrated as observed, for example in a submerged membrane adsorption hybrid system (SMAHS). It uses coarse air bubbling/sparging to produce local shear which minimises reversible membrane fouling, improves performance and extends the life of the membrane. Additionally, the adsorbent acts as a buoyant media that produces an extra shearing effect on the membrane surface, reduces membrane resistance and increases flux. In addition, it adsorbs the organics that would otherwise deposit on and cause fouling of the membrane. The use of activated carbon (AC) adsorbent in SMAHS is very effective in removing most pollutants including natural organic matter (NOM) and organic micropollutants (OMPs) from wastewaters and membrane concentrate wastes, the latter being a serious problem in practical applications of the reverse osmosis process. However, certain NOM fractions and OMPs (i.e. hydrophilic and negatively charged ones) are not efficiently removed by AC. Other adsorbents need to be explored for their effective removal.

摘要

清洁水短缺是一个全球性的主要问题,这是由于人口增长和工业活动导致需求不断增加,淡水资源减少以及持续干旱等原因造成的。采用高效的回灌技术对废水进行回收和再利用可以帮助解决这个问题。然而,废水中含有多种污染物,在再次使用之前需要去除。吸附和膜处理是两种成功的处理方法,可用于去除这些污染物中的大部分。如在浸没式膜吸附混合系统(SMAHS)中观察到的那样,当这些过程被集成时,它们的效率会提高。该系统使用粗空气鼓泡/喷射产生局部剪切,从而最大程度地减少可逆膜污染,提高性能并延长膜的使用寿命。此外,吸附剂作为浮性介质,在膜表面产生额外的剪切作用,降低膜阻力并增加通量。此外,它还吸附原本会沉积在膜上并导致膜污染的有机物。在 SMAHS 中使用活性炭(AC)吸附剂非常有效,可以去除废水中的大多数污染物,包括天然有机物(NOM)和有机微污染物(OMP),以及反渗透过程实际应用中存在的膜浓缩废物这一严重问题。然而,某些 NOM 分数和 OMP(即亲水性和带负电荷的物质)不能被 AC 有效去除。需要探索其他吸附剂来有效去除这些物质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8ae/10076408/b32b45c12f98/11356_2022_23229_Fig1_HTML.jpg

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