A Robust, Flexible, Hydrophobic, and Multifunctional Pressure Sensor Based on an MXene/Aramid Nanofiber (ANF) Aerogel Film.

Pressure sensors with desirable flexibility, robustness, and versatility are urgently needed for complicated smart wearable devices. However, developing an ideal multifunctional flexible sensor is still challenging. In this work, a composite aerogel film sensor with an internal three-dimensional (3D) microporous and hierarchical structure is successfully fabricated by the self-assembly of aramid nanofiber (ANF) and conductive MXene by vacuum-assisted filtration and ice crystal growth. The resultant MXene/ANF aerogel film with a mass ratio of 3/7 (30% MAAF) presents high robustness with an outstanding tensile strength of 14.1 MPa and a modulus of 455 MPa while retaining appealing flexibility and sensitive characteristics due to the 3D microstructure. Accompanied by superior electric conductivity, the MAAF sensor performs noticeably in human motion and microexpression detection with a fast response time of 100 ms and a high sensitivity of 37.4 kPa. In addition, MAAF exhibits considerable thermal shielding performance based on the excellent thermostability. Moreover, it possesses prominent electrothermal property with a wide heating temperature range (32.7-242 °C) in a fast thermal response time (5 s) due to the Joule effect. Additionally, a hydrophobic SiO coating is introduced on the surface of MAAF to further broaden the sensing application, and the obtained MAAF@SiO sensor shows distinguished sensing capability underwater, which can be accurately applied to swimming monitoring. Therefore, this work provides a highly flexible, lightweight, robust, and multifunctional aerogel film sensor, showing promising potential in smart wearable sensing and healthcare devices, intelligent robots, and underwater detection.