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线性和非线性回归分析用于研究罗马尼亚啤酒厂副产物对雷马唑染料的吸附作用,。

Linear and Nonlinear Regression Analysis for the Adsorption of Remazol Dye by Romanian Brewery Waste By-Product, .

机构信息

Environmental Science Department, Sapientia Hungarian University of Transylvania, Calea Turzii no. 4, 400193 Cluj-Napoca, Romania.

出版信息

Int J Mol Sci. 2022 Oct 5;23(19):11827. doi: 10.3390/ijms231911827.

Abstract

Earth's water balance and economy are becoming increasingly fragile due to overpopulation, global warming, severe environmental pollution and both surface and groundwater pollution. Therefore, it is essential to find solutions to the problems of water scarcity and water pollution. In this research, an experiment was designed to optimize the technique for the adsorption of Remazol Red F3B (RR) dye by lyophilized brewery yeast waste from the fermentation process. Moreover, we proved that brewery yeast is a great adsorbent. Batch adsorption experiments were carried out for optimization of different initial parameters, such as initial dye concentration (5-1000 mg/L), amount of yeast (0.5-2.5 g), pH (3-11) and temperature (20 to 40 °C). Furthermore, the structure and elemental composition of the adsorbent were analyzed with SEM, EDS and FTIR before and after biosorption. The best fits for the mathematical isotherm models in the case of the linear form were the Langmuir I and Freundlich models (R = 0.923 and R = 0.921) and, for the nonlinear form, the Khan model (R = 0.9996) was the best fit. The pseudo-second-order kinetic model showed the best fit for both linear (plotting t/q vs. t) and nonlinear forms, are the calculated q values were similar to the experimental data.

摘要

由于人口过剩、全球变暖、严重的环境污染以及地表水和地下水的污染,地球的水平衡和经济正变得越来越脆弱。因此,寻找解决水资源短缺和水污染问题的方法至关重要。在这项研究中,设计了一个实验,以优化从发酵过程中冻干啤酒厂酵母废物吸附 Remazol Red F3B(RR)染料的技术。此外,我们证明了啤酒酵母是一种很好的吸附剂。进行了批量吸附实验,以优化不同的初始参数,如初始染料浓度(5-1000mg/L)、酵母用量(0.5-2.5g)、pH(3-11)和温度(20-40°C)。此外,在生物吸附前后用 SEM、EDS 和 FTIR 分析了吸附剂的结构和元素组成。线性形式下,最佳拟合的数学等温线模型是 Langmuir I 和 Freundlich 模型(R = 0.923 和 R = 0.921),而对于非线性形式,Khan 模型(R = 0.9996)是最佳拟合。准二级动力学模型对线性(绘制 t/q 与 t)和非线性形式都表现出最佳拟合,计算得到的 q 值与实验数据相似。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c8/9570003/b168bfbf8462/ijms-23-11827-g001.jpg

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