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用于油气钻采工程的聚合物凝胶

Polymer Gels Used in Oil-Gas Drilling and Production Engineering.

作者信息

Han Jinliang, Sun Jinsheng, Lv Kaihe, Yang Jingbin, Li Yuhong

机构信息

School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China.

Institute of Engineering and Technology, PetroChina Coalbed Methane Company Limited, Xi'an 710082, China.

出版信息

Gels. 2022 Oct 7;8(10):637. doi: 10.3390/gels8100637.

DOI:10.3390/gels8100637
PMID:36286138
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9602122/
Abstract

Polymer gels are widely used in oil-gas drilling and production engineering for the purposes of conformance control, water shutoff, fracturing, lost circulation control, etc. Here, the progress in research on three kinds of polymer gels, including the in situ crosslinked polymer gel, the pre-crosslinked polymer gel and the physically crosslinked polymer gel, are systematically reviewed in terms of the gel compositions, crosslinking principles and properties. Moreover, the advantages and disadvantages of the three kinds of polymer gels are also comparatively discussed. The types, characteristics and action mechanisms of the polymer gels used in oil-gas drilling and production engineering are systematically analyzed. Depending on the crosslinking mechanism, in situ crosslinked polymer gels can be divided into free-radical-based monomer crosslinked gels, ionic-bond-based metal cross-linked gels and covalent-bond-based organic crosslinked gels. Surface crosslinked polymer gels are divided into two types based on their size and gel particle preparation method, including pre-crosslinked gel particles and polymer gel microspheres. Physically crosslinked polymer gels are mainly divided into hydrogen-bonded gels, hydrophobic association gels and electrostatic interaction gels depending on the application conditions of the oil-gas drilling and production engineering processes. In the field of oil-gas drilling engineering, the polymer gels are mainly used as drilling fluids, plugging agents and lost circulation materials, and polymer gels are an important material that are utilized for profile control, water shutoff, chemical flooding and fracturing. Finally, the research potential of polymer gels in oil-gas drilling and production engineering is proposed. The temperature resistance, salinity resistance, gelation strength and environmental friendliness of polymer gels should be further improved in order to meet the future technical requirements of oil-gas drilling and production.

摘要

聚合物凝胶在油气钻采工程中被广泛用于调剖、堵水、压裂、堵漏等目的。在此，从凝胶组成、交联原理和性能方面，系统综述了包括原位交联聚合物凝胶、预交联聚合物凝胶和物理交联聚合物凝胶这三种聚合物凝胶的研究进展。此外，还对这三种聚合物凝胶的优缺点进行了比较讨论。系统分析了油气钻采工程中使用的聚合物凝胶的类型、特点及作用机理。根据交联机理，原位交联聚合物凝胶可分为自由基型单体交联凝胶、离子键型金属交联凝胶和共价键型有机交联凝胶。表面交联聚合物凝胶根据其尺寸和凝胶颗粒制备方法分为两类，包括预交联凝胶颗粒和聚合物凝胶微球。物理交联聚合物凝胶根据油气钻采工程过程的应用条件主要分为氢键凝胶、疏水缔合凝胶和静电相互作用凝胶。在油气钻井工程领域，聚合物凝胶主要用作钻井液、堵漏剂和堵漏材料，聚合物凝胶是用于调剖、堵水、化学驱油和压裂的重要材料。最后，提出了聚合物凝胶在油气钻采工程中的研究潜力。为满足未来油气钻采的技术要求，应进一步提高聚合物凝胶的耐温性、耐盐性、凝胶强度和环境友好性。

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