Zhao Zhiwei, He Wei, Wu Ruilin, Xu Fuliu
MOE Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China.
Beijing Key Laboratory of Water Resources & Environmental Engineering, China University of Geosciences (Beijing), Beijing100083, China.
Toxics. 2022 Sep 30;10(10):577. doi: 10.3390/toxics10100577.
The distributions and correlations among polycyclic aromatic hydrocarbons (PAHs) in soils and plants were analyzed. In this study, 9 soil samples and 44 plant samples were collected near major lakes (Hongze Lake, Luoma Lake, Chaohu, Changhu, Danjiangkou Reservoir, Wuhan East Lake, Longgan Lake, Qiandao Lake and Liangzi Lake) in eastern China. The following results were obtained: The total contents of PAHs in soil varied from 99.17 to 552.10 ng/g with an average of 190.35 ng/g, and the total contents of PAHs in plants varied from 122.93 to 743.44 ng/g, with an average of 274.66 ng/g. The PAHs in soil were dominated by medium- and low-molecular-weight PAHs, while the PAHs in plants were dominated by low-molecular-weight PAHs. The proportion of high-molecular-weight PAHs was the lowest in both soil and plants. Diagnostic ratios and principal component analysis (PCA) identified combustion as the main source of PAHs in soil and plants. The plant PAH monomer content was negatively correlated with Koa. Acenaphthylene, anthracene, benzo[k]fluoranthene, benzo[b]fluoranthene and dibenzo[a,h]anthracene were significantly correlated in plants and soil. In addition, no significant correlation between the total contents of the 16 PAHs and the content of high-, medium-, and low-molecular-weight PAHs in plants and soil was found. L. and Foug in the Compositae family and cron in the Poaceae family showed relatively stronger accumulation of PAHs, indicating their potential for phytoremediation.
分析了土壤和植物中多环芳烃(PAHs)的分布及相关性。本研究在中国东部主要湖泊(洪泽湖、骆马湖、巢湖、长湖、丹江口水库、武汉东湖、龙感湖、千岛湖和梁子湖)附近采集了9个土壤样品和44个植物样品。得到以下结果:土壤中PAHs的总含量在99.17至552.10 ng/g之间,平均为190.35 ng/g;植物中PAHs的总含量在122.93至743.44 ng/g之间,平均为274.66 ng/g。土壤中的PAHs以中低分子量PAHs为主,而植物中的PAHs以低分子量PAHs为主。土壤和植物中高分子量PAHs的比例均最低。诊断比值和主成分分析(PCA)确定燃烧是土壤和植物中PAHs的主要来源。植物PAH单体含量与Koa呈负相关。苊烯、蒽、苯并[k]荧蒽、苯并[b]荧蒽和二苯并[a,h]蒽在植物和土壤中显著相关。此外,未发现16种PAHs的总含量与植物和土壤中高、中、低分子量PAHs含量之间存在显著相关性。菊科的L.和Foug以及禾本科的cron对PAHs的积累相对较强,表明它们具有植物修复的潜力。