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含镨钕铬仿宝石玻璃的制备及基本性能

Preparation and Basic Properties of Praseodymium-Neodymium-Chromium Containing Imitation Gemstone Glass.

作者信息

Zhang Siqi, Li Keqing, Pu Junyuan, Ni Wen

机构信息

School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China.

National Gems & Jewelry Testing Group Training Center Shanghai Branch, Shanghai 200021, China.

出版信息

Materials (Basel). 2022 Oct 20;15(20):7341. doi: 10.3390/ma15207341.

Abstract

Imitation gemstone glass has numerous characteristics, including low cost, rich colour, stable colouring, and the formation of colour-changing effects that can meet the jewellery market demand for beautiful gemstones of middle and low grades. In this study, four types of gem-imitating glass were prepared by the elemental substitution of praseodymium, neodymium and chromium elements based on rare earth glass and examined by combining refractive index, density, spectral characteristics and colour parameters. Sample 1 contained only PrO and showed a golden-yellow colour like chrysoberyl. Sample 2 contained only NdO and showed a blue-purple colour like amethyst. Sample 3 contained PrO and NdO and appeared green under D65 light source and red under A light source, with a colour-change effect like alexandrite. Sample 4 contained PrO, NdO and CrO and showed a highly saturated green colour like emerald because of the strong colouring effect of Cr in the glass. The findings revealed that all four samples are transparent, with a refractive index greater than 1.5 and a density higher than 2.6 g/cm. The comprehensive performance of the four imitation gemstone glasses can be found in the corresponding natural gemstones, which has a certain practical value.

摘要

仿宝石玻璃具有诸多特性,包括成本低、颜色丰富、成色稳定以及能形成变色效果,可满足珠宝市场对中低档次美观宝石的需求。在本研究中,基于稀土玻璃通过镨、钕和铬元素的元素替代制备了四种仿宝石玻璃,并结合折射率、密度、光谱特性和颜色参数进行了检测。样品1仅含PrO,呈现出类似金绿宝石的金黄色。样品2仅含NdO,呈现出类似紫水晶的蓝紫色。样品3含PrO和NdO,在D65光源下呈绿色,在A光源下呈红色,具有类似变石的变色效果。样品4含PrO、NdO和CrO,由于玻璃中Cr的强烈着色作用,呈现出类似祖母绿的高饱和度绿色。研究结果表明,所有四个样品均透明,折射率大于1.5,密度高于2.6 g/cm³。这四种仿宝石玻璃的综合性能在相应天然宝石中均可找到,具有一定的实用价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efcd/9611999/85348b2043e1/materials-15-07341-g004.jpg

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