Jung Dong Geon, Lee Junyeop, Kwon Jin Beom, Maeng Bohee, An Hee Kyung, Jung Daewoong
Advanced Mechatronics R&D Group, Korea Institute of Industrial Technology (KITECH), Seoul 31056, Korea.
Micromachines (Basel). 2022 Sep 27;13(10):1609. doi: 10.3390/mi13101609.
To realize portable gas sensor applications, it is necessary to develop hydrogen sulfide (H2S) microsensors capable of operating at lower voltages with high response, good selectivity and stability, and fast response and recovery times. A gas sensor with a high operating voltage (>5 V) is not suitable for portable applications because it demands additional circuitry, such as a charge pump circuit (supply voltage of common circuits is approximately 1.8−5 V). Among H2S microsensor components, that is, the substrate, sensing area, electrode, and micro-heater, the proper design of the micro-heater is particularly important, owing to the role of thermal energy in ensuring the efficient detection of H2S. This study proposes and develops tin (IV)-oxide (SnO2)-based H2S microsensors with different geometrically designed embedded micro-heaters. The proposed micro-heaters affect the operating temperature of the H2S sensors, and the micro-heater with a rectangular mesh pattern exhibits superior heating performance at a relatively low operating voltage (3−4 V) compared to those with line (5−7 V) and rectangular patterns (3−5 V). Moreover, utilizing a micro-heater with a rectangular mesh pattern, the fabricated SnO2-based H2S microsensor was driven at a low operating voltage and offered good detection capability at a low H2S concentration (0−10 ppm), with a quick response (<51 s) and recovery time (<101 s).
为实现便携式气体传感器的应用,有必要开发能够在较低电压下工作的硫化氢(H₂S)微传感器,这些微传感器需具备高响应性、良好的选择性和稳定性,以及快速的响应和恢复时间。工作电压高(>5V)的气体传感器不适用于便携式应用,因为它需要额外的电路,如电荷泵电路(常见电路的电源电压约为1.8−5V)。在H₂S微传感器组件中,即基板、传感区域、电极和微加热器,微加热器的合理设计尤为重要,这是因为热能在确保高效检测H₂S方面发挥着作用。本研究提出并开发了具有不同几何设计嵌入式微加热器的基于二氧化锡(SnO₂)的H₂S微传感器。所提出的微加热器会影响H₂S传感器的工作温度,与具有线状图案(5−7V)和矩形图案(3−5V)的微加热器相比,具有矩形网格图案的微加热器在相对较低的工作电压(3−4V)下表现出卓越的加热性能。此外,利用具有矩形网格图案的微加热器,制造出的基于SnO₂的H₂S微传感器在低工作电压下驱动,在低H₂S浓度(0−10ppm)下具有良好的检测能力,响应迅速(<51s)且恢复时间短(<101s)。