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氧化锌/氮化硼量子点纳米复合材料用于增强亚甲基蓝和甲基橙的光催化降解。

ZnO/Boron Nitride Quantum Dots Nanocomposites for the Enhanced Photocatalytic Degradation of Methylene Blue and Methyl Orange.

机构信息

School of Chemical Engineering, University of Ulsan, 93 Daehak-ro Nam-gu, Ulsan 44610, Korea.

出版信息

Molecules. 2022 Oct 12;27(20):6833. doi: 10.3390/molecules27206833.

Abstract

In this study, a heterostructure photocatalyst of ZnO nanoparticles decorated with boron nitride quantum dots (ZnO/BNQDs) was successfully synthesized by a simple solution procedure. The synthesized ZnO/BNQDs show that the BNQDs effectively suppress the recombination of photoinduced electrons and holes and the transfer of holes from ZnO nanoparticles by the formation of a heterojunction. The ZnO/BNQD nanocomposites thus demonstrate superior photocatalytic performances and excellent stability for the degradation of methylene blue (MB) and methyl orange (MO) under UV light irradiation. Based on the obtained results, the possible photocatalytic mechanism is proposed and discussed. Thus, the ZnO/BNQD nanocomposites demonstrate potential as an efficient low-cost photocatalyst for application in the photodegradation of organic dyes in wastewater for environmental remediation.

摘要

在这项研究中,通过简单的溶液法成功合成了 ZnO 纳米粒子修饰的氮化硼量子点(ZnO/BNQDs)异质结构光催化剂。合成的 ZnO/BNQDs 表明,BNQDs 通过形成异质结,有效地抑制了光生电子和空穴的复合以及从 ZnO 纳米粒子转移的空穴。因此,ZnO/BNQD 纳米复合材料在紫外光照射下对亚甲基蓝(MB)和甲基橙(MO)的降解表现出优异的光催化性能和优异的稳定性。基于获得的结果,提出并讨论了可能的光催化机理。因此,ZnO/BNQD 纳米复合材料作为一种高效、低成本的光催化剂,有望应用于废水有机染料的光降解,用于环境修复。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e32/9612324/c1df27c1bda9/molecules-27-06833-g001.jpg

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