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蛋白质粘合剂:影响经碱处理的蛋白质与乙二醛交联后的湿强度的因素研究。

Protein Adhesives: Investigation of Factors Affecting Wet Strength of Alkaline Treated Proteins Crosslinked with Glyoxal.

作者信息

Averina Elena, Konnerth Johannes, van Herwijnen Hendrikus W G

机构信息

Institute of Wood Technology and Renewable Materials, Department of Material Sciences and Process Engineering, University of Natural Resources and Life Science, Konrad-Lorenz-Strasse 24, 3430 Tulln an der Donau, Austria.

Wood K Plus-Kompetenzzentrum Holz GmbH, Altenberger Straße 69, 4040 Linz, Austria.

出版信息

Polymers (Basel). 2022 Oct 15;14(20):4351. doi: 10.3390/polym14204351.

Abstract

Proteins obtained as side-products from starch production (potato and corn proteins) were investigated for wood adhesives application. To improve the wet strength of protein-based adhesives, glyoxal was added as a crosslinking agent. The effect of glyoxal on the wet strength of protein-based adhesives was investigated at different pH, protein: glyoxal ratios and solid content. The alkaline pretreatment of proteins was carried out by two different methods which reduced the molecular weight of proteins to different extents. The effect of molecular weight reduction on the wet strength of protein-glyoxal adhesives was also observed. It was found that pH level affects wet strength more significantly compared to solid content and protein-to-crosslinker ratio. Potato and corn proteins crosslinked with glyoxal showed maximal wet strength results in an acidic pH range.

摘要

对淀粉生产过程中作为副产品获得的蛋白质(马铃薯蛋白和玉米蛋白)进行了木材胶粘剂应用方面的研究。为提高蛋白质基胶粘剂的湿强度,添加了乙二醛作为交联剂。在不同的pH值、蛋白质与乙二醛的比例以及固含量下,研究了乙二醛对蛋白质基胶粘剂湿强度的影响。采用两种不同方法对蛋白质进行碱性预处理,这两种方法使蛋白质分子量降低的程度不同。还观察了分子量降低对蛋白质 - 乙二醛胶粘剂湿强度的影响。结果发现,与固含量和蛋白质与交联剂的比例相比,pH值对湿强度的影响更为显著。用乙二醛交联的马铃薯蛋白和玉米蛋白在酸性pH范围内显示出最大的湿强度结果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/287f/9612214/b7e938ad8a2f/polymers-14-04351-g001.jpg

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