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硅纳米锥上的ITO/Si/ITO半锥壳手性复合物,在中红外波长具有宽带圆二色性。

ITO/Si/ITO semi-cone-shell chiral complexes on silicon nanocones with broadband circular dichroism in the mid-infrared wavelength.

作者信息

Li Cheng, Liu Jing, Li Liang, Cui Qi, Zhang Yu-Jun, Wu Ying, Han Cai-Qin, Yan Chang-Chun

出版信息

Opt Express. 2022 Oct 24;30(22):40925-40935. doi: 10.1364/OE.472656.

Abstract

This paper proposed ITO/Si/ITO semi-cone-shell chiral complexes on silicon nanocones with broadband CD in the mid-infrared band. The experimental results show that when the deposition angle θ = 45°, the first ITO deposition of t = 100 nm, the second Si deposition of t = 200 nm with the azimuth angle unchanged, and the third ITO deposition of t = 200 nm after rotating the azimuth angle of 60°, the prepared chiral structure has a broadband CD response in the mid-infrared band of 2.5-4 µm. The broadband CD effect is produced by the internal resonance of the three-dimensional open cavity. The cone structure can be regarded as a plurality of planar open resonant rings with different diameters, and these rings resonate at different wavelengths. The experimental results also show that the proposed chiral ITO structure exhibits a better broadband CD response than that of the structure composed of traditional metal Ag. Such a chiral structure provides a new method for the design of CD devices in the mid-infrared band.

摘要

本文提出了一种在硅纳米锥上制备的具有中红外波段宽带圆二色性(CD)的ITO/Si/ITO半锥壳手性复合物。实验结果表明,当沉积角θ = 45°时,第一次ITO沉积厚度t = 100 nm,第二次Si沉积厚度t = 200 nm且方位角不变,第三次ITO沉积厚度t = 200 nm且方位角旋转60°后,所制备的手性结构在2.5 - 4 µm的中红外波段具有宽带CD响应。宽带CD效应是由三维开放腔的内部共振产生的。锥形结构可视为多个不同直径的平面开放谐振环,这些环在不同波长处发生共振。实验结果还表明,所提出的手性ITO结构比传统金属Ag组成的结构表现出更好的宽带CD响应。这种手性结构为中红外波段CD器件的设计提供了一种新方法。

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