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基于单组分发射体芳香族碳氮化物的暖白色发光二极管。

A warm-white light-emitting diode based on single-component emitter aromatic carbon nitride.

作者信息

Wang Yunhu, Wang Kunpeng, Dai Fangxu, Zhang Kai, Tang Haifeng, Wang Lei, Xing Jun

机构信息

Key Laboratory of Eco-chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, 266042, Qingdao, China.

Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science & Technology, 266042, Qingdao, China.

出版信息

Nat Commun. 2022 Oct 30;13(1):6495. doi: 10.1038/s41467-022-34291-9.

Abstract

Artificial lighting consumes almost one-fifth of global electricity. As an efficient solid-state lighting technology, white light-emitting diodes (WLEDs) have received increasing attention. However, the white luminescence of the traditional WLEDs comes from multi-component emitters, which leads to complex device structure and unstable emitting color. Therefore, developing single-component materials with white-light electroluminescence is of significance for artificial lighting applications. Here, we fabricate single-component white-light electroluminescence devices based on an aromatic carbon nitride material and improve the performance of WLEDs by adjusting the carrier transport. The carbon nitride LEDs emit warm-white light, of which color coordinates and color temperature are (0.44, 0.52) and 3700 K. The optimized LEDs display a very low turn-on voltage of 3.2 V and achieve a milestone in the maximum luminance and external quantum efficiency of 1885 cd m and 1.20%. Our findings demonstrate the low-cost carbon nitride materials have promising potential for single-component WLEDs application.

摘要

人工照明消耗了全球近五分之一的电力。作为一种高效的固态照明技术,白光发光二极管(WLED)受到了越来越多的关注。然而,传统WLED的白色发光来自多组分发光体,这导致器件结构复杂且发光颜色不稳定。因此,开发具有白色电致发光的单组分材料对于人工照明应用具有重要意义。在此,我们基于一种芳香族氮化碳材料制备了单组分白色电致发光器件,并通过调节载流子传输来提高WLED的性能。氮化碳发光二极管发出暖白光,其色坐标和色温分别为(0.44, 0.52)和3700 K。优化后的发光二极管显示出非常低的开启电压3.2 V,并在最大亮度和外量子效率方面达到了1885 cd m和1.20%的里程碑。我们的研究结果表明,低成本的氮化碳材料在单组分WLED应用中具有广阔的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4ab/9618563/235ca8a8034e/41467_2022_34291_Fig1_HTML.jpg

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