Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction.

In this work, a CdS/BiVO step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions, which allows CdS/BiVO to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BiVO. Experimental results such as radical quenching experiments and electron spin resonance show that U(VI) is rapidly oxidized by photoholes/OH to insoluble UO(OH) after being reduced to U(IV) by photoelectrons/O , which precisely avoids the depletion of electron sacrificial agents. The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis. This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.