General and Robust Photothermal-Heating-Enabled High-Efficiency Photoelectrochemical Water Splitting.

The ability of photoanodes to simultaneously tailor light absorption, charge separation, and water oxidation processes represents an important endeavor toward highly efficient photoelectrochemical (PEC) water splitting. Here, a robust strategy is reported to render markedly improved PEC water splitting via sandwiching a photothermal Co O layer between a BiVO photoanode film and an FeOOH/NiOOH electrocatalyst sheet. The deposited Co O layer manifests compelling photothermal effect upon near-infrared irradiation and raises the temperature of the photoanodes in situ, leading to extended light absorption, enhanced charge transfer, and accelerated water oxidation kinetics simultaneously. The judiciously designed NiOOH/FeOOH/Co O /BiVO photoanode renders a superior photocurrent density of 6.34 mA cm at 1.23 V versus a reversible reference electrode (V ) with outstanding applied bias photon-to-current efficiency of 2.72% at 0.6 V . In addition to the metal oxide, a wide variety of metal sulfides, nitrides, and phosphides (e.g., CoS, CoN, and CoP) can be exploited as the heaters to yield high-performance BiVO -based photoanodes. Apart from BiVO , other metal oxides (e.g., Fe O and TiO ) can also be covered by photothermal materials to impart significantly promoted water splitting. This simple yet general strategy provides a unique platform to capitalize on their photothermal characteristics to engineer high-performing energy conversion and storage materials and devices.