Dubi Yonatan
Department of Chemistry, Ben Gurion University of the Negev Be'er Sheva Israel 8410501
Ilse Katz Center for Nanoscale Science and Technology, Ben Gurion University of the Negev Be'er Sheva Israel 8410501.
Chem Sci. 2022 Aug 16;13(36):10878-10883. doi: 10.1039/d2sc02565e. eCollection 2022 Sep 21.
The chirality-induced spin selectivity (CISS) effect, namely the dependence of current through a chiral molecule on spin of the electron, was discovered over two decades ago, and has been suggested for various spin- and chirality-related applications. Yet, quite surprisingly, its physical origin remains elusive, and no theoretical description can quantitatively describe it. Here, we propose a theory for the CISS effect in bio-molecular junctions, based on the interplay between spin-orbit coupling in the electrodes, molecular chirality and spin-transfer torque across the electrode-molecule interface. This theory leads to the first ever quantitative analysis of experimental data, and provides insights into the origin of the CISS effect. The theory presented here can be used to analyze past experiments and to design new experiments, which may lead to deeper understanding of what is considered one of the outstanding problems in molecular electronics and nano-scale transport.
手性诱导自旋选择性(CISS)效应,即通过手性分子的电流对电子自旋的依赖性,是二十多年前发现的,并已被用于各种与自旋和手性相关的应用中。然而,令人惊讶的是,其物理起源仍然难以捉摸,尚无理论描述能够对其进行定量描述。在此,我们基于电极中的自旋轨道耦合、分子手性以及跨电极 - 分子界面的自旋转移转矩之间的相互作用,提出了一种生物分子结中CISS效应的理论。该理论首次对实验数据进行了定量分析,并深入探讨了CISS效应的起源。这里提出的理论可用于分析过去的实验并设计新的实验,这可能有助于更深入地理解分子电子学和纳米尺度输运中被认为是突出问题之一的现象。