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3-(2,3-二甲氧基苯基)-2,3-二氢-1-苯并[b]色烯-1-酮

3-(2,3-Di-meth-oxy-phen-yl)-2,3-di-hydro-1-benzo[]chromen-1-one.

作者信息

Sung Jiha

机构信息

Department of Applied Chemistry, Dongduk Women's University, Seoul 136-714, Republic of Korea.

出版信息

IUCrdata. 2022 Sep 13;7(Pt 9):x220885. doi: 10.1107/S2414314622008859. eCollection 2022 Sep.

Abstract

In the title compound, CHO, the central pyran ring is in an envelope conformation and the dihedral angle between the benzene ring and naphthalene ring system is 88.31 (1)°. The meth-oxy groups at the and positions of the benzene ring are tilted to the ring with C-C-O-C torsion angles of 105.9 (4) and 9.5 (5)°, respectively. In the crystal, pairwise C-H⋯O hydrogen bonds form (14) inversion dimers, which are linked by another pair of C-H⋯O hydrogen bonds to form [210] chains in the crystal.

摘要

在标题化合物CHO中,中心吡喃环呈信封构象,苯环与萘环体系之间的二面角为88.31 (1)°。苯环和位置的甲氧基分别以105.9 (4)°和9.5 (5)°的C-C-O-C扭转角向环倾斜。在晶体中,成对的C-H⋯O氢键形成(14)反演二聚体,这些二聚体通过另一对C-H⋯O氢键相连,在晶体中形成[210]链。

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