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3-(2,3-二甲氧基苯基)-2,3-二氢-1-苯并[b]色烯-1-酮

3-(2,3-Di-meth-oxy-phen-yl)-2,3-di-hydro-1-benzo[]chromen-1-one.

作者信息

Sung Jiha

机构信息

Department of Applied Chemistry, Dongduk Women's University, Seoul 136-714, Republic of Korea.

出版信息

IUCrdata. 2022 Sep 13;7(Pt 9):x220885. doi: 10.1107/S2414314622008859. eCollection 2022 Sep.

DOI:10.1107/S2414314622008859
PMID:36337455
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635425/
Abstract

In the title compound, CHO, the central pyran ring is in an envelope conformation and the dihedral angle between the benzene ring and naphthalene ring system is 88.31 (1)°. The meth-oxy groups at the and positions of the benzene ring are tilted to the ring with C-C-O-C torsion angles of 105.9 (4) and 9.5 (5)°, respectively. In the crystal, pairwise C-H⋯O hydrogen bonds form (14) inversion dimers, which are linked by another pair of C-H⋯O hydrogen bonds to form [210] chains in the crystal.

摘要

在标题化合物CHO中,中心吡喃环呈信封构象,苯环与萘环体系之间的二面角为88.31 (1)°。苯环和位置的甲氧基分别以105.9 (4)°和9.5 (5)°的C-C-O-C扭转角向环倾斜。在晶体中,成对的C-H⋯O氢键形成(14)反演二聚体,这些二聚体通过另一对C-H⋯O氢键相连,在晶体中形成[210]链。

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