Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, Siegen D-57068, Germany.
Institut für Organische Chemie und Chemische Biologie, Johann Wolfgang Goethe-Universität, Max-von-Laue Strasse 7, Frankfurt am Main D-60438, Germany.
Chem Commun (Camb). 2022 Nov 22;58(93):13019-13022. doi: 10.1039/d2cc04497h.
The HETPYNE (HETeroleptic Phenanthroline and alkYNE metal) and DABCO·(zinc porphyrin) interactions were used to assemble the four-component nanorotor ROT-1 that exhibited a highly dynamic alkyne → copper(I) dissociation ( = 240 kHz) at 298 K. Quantitative click reaction transformed ROT-1 into the new rotor ROT-2 ( = 77 kHz) with a triazole → copper(I) linkage thus opening perspectives for bioorthogonal click strategies to biohybrid machinery.
使用 HETPYNE（杂环菲咯啉和炔烃金属）和 DABCO·（锌卟啉）相互作用将四组分纳米转子 ROT-1 组装在一起，该转子在 298 K 时表现出高度动态的炔烃→铜（I）解离（ = 240 kHz）。定量点击反应将 ROT-1 转化为具有三唑→铜（I）键的新转子 ROT-2（ = 77 kHz），从而为生物正交点击策略开辟了用于生物杂交机械的前景。
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