基于棱柱[5]芳烃烷氧基同系物的手性光诱导
Chiroptical induction with prism[5]arene alkoxy-homologs.
作者信息
Liang Xiaotong, Shen Yanling, Zhou Dayang, Ji Jiecheng, Wang Hongtao, Zhao Ting, Mori Tadashi, Wu Wanhua, Yang Cheng
机构信息
College of Architecture and Environment, Huaxi MR Research Center (HMRRC), Department of Radiology, West China Hospital, and Key Laboratory of Green Chemistry & Technology of Ministry of Education, Sichuan University, Chengdu 610064, China.
Department of Applied Chemistry, and Comprehensive Analysis Center, ISIR, Osaka University, Yamada-oka, Suita 565-0871, Japan.
出版信息
Chem Commun (Camb). 2022 Dec 8;58(98):13584-13587. doi: 10.1039/d2cc05690a.
The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 10 M, significant CD with of up to 0.8 × 10 and CPL with of 2 × 10. The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes.
柱[5]芳烃与氨基酸衍生物的络合显示出高达10 M的缔合常数、高达0.8×10的显著圆二色性（CD）以及2×10的圆偏振发光（CPL）。建立了绝对构型与CD信号的相关性。CD光谱随柱[5]芳烃上的取代基而显著变化。
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