具有NADH模拟功能化金属有机胶囊的光开关选择性催化
Light-switched selective catalysis with NADH mimic functionalized metal-organic capsules.
作者信息
Wei Jianwei, Zhao Liang, Zhang Yu, Zhou Peng, Liu Guangzhou, Duan Chunying
机构信息
State Key Laboratory of Fine Chemicals, Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, P. R. China.
出版信息
Chem Commun (Camb). 2022 Dec 22;59(1):71-74. doi: 10.1039/d2cc04530c.
By incorporating an active site model of nicotinamide adenine dinucleotide (NADH) as an electron regulator, a redox-active metal-organic capsule as an efficient photocatalyst was obtained for the light switchable synthesis of a series of aromatic azoxy and amino compounds from their corresponding nitroaromatics under either purple (420 nm) or blue (455 nm) LED light irradiation.
通过将烟酰胺腺嘌呤二核苷酸（NADH）的活性位点模型作为电子调节剂，获得了一种氧化还原活性金属有机胶囊作为高效光催化剂，用于在紫色（420 nm）或蓝色（455 nm）发光二极管光照下，从相应的硝基芳烃光开关合成一系列芳族氧化偶氮化合物和氨基化合物。
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