LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol.

The present study outlines the transformation of non-photoresponsive hexagonal boron nitride (HBN) into a visible-light-responsive material. The carbon modification was achieved through a solid-state reaction procedure inside a tube furnace under nitrogen atmosphere. In comparison to HBN (bandgap of 5.2 eV), the carbon-modified boron nitride could efficiently absorb LED light irradiation with a light harvesting efficiency of ≈90% and a direct bandgap of 2 eV. The introduction of carbon into the HBN lattice led to a significant change in the electronic environment through the formation of C-B and C-N bonds which resulted in improved visible light activity, lower charge transfer resistance, and improved charge carrier density (2.97 × 10 cm). This subsequently enhanced the photocurrent density (three times) and decreased the photovoltage decay time (two times) in comparison to those of HBN. The electronic band structure (obtained through Mott-Schottky plots) and charge trapping analysis confirmed the dominance of e, O , and OH as dominant reactive oxygen species. The carbon modification could effectively remove 93.83% of methylene blue (MB, 20 ppm solution) and 48.56% of phenol (10 ppm solution) from the aqueous phase in comparison to HBN which shows zero activity in the visible region.