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掺入二氧化钛废料作为钢结构被动防火绝缘材料的粉煤灰地质聚合物的物理、力学和放射学特性

Physical, Mechanical and Radiological Characteristics of a Fly Ash Geopolymer Incorporating Titanium Dioxide Waste as Passive Fire Insulating Material in Steel Structures.

作者信息

Salazar Pedro Antonio, Fernández Carlos Leiva, Luna-Galiano Yolanda, Sánchez Rosario Villegas, Fernández-Pereira Constantino

机构信息

Chemical and Environmental Engineering Department, School of Engineering, University of Seville, Camino de los Descubrimientos s/n 41092, 41092 Seville, Spain.

出版信息

Materials (Basel). 2022 Nov 29;15(23):8493. doi: 10.3390/ma15238493.

Abstract

This research analyzes whether a titanium dioxide waste (TiO waste) can be used as a source material for geopolymers with good fire resistance properties. Samples with different proportions were prepared, replacing fly ashes with titanium dioxide waste on geopolymers (0, 20, 30, 40 and 100% /). The activating solution has a NaO/SiO molar ratio of 0.98. Physical (bulk density, moisture content and water absorption) and mechanical (superficial hardness and compressive strength) characteristics have been evaluated. In addition, their thermal behavior at high temperatures (fire resistance, compressive strength at elevated temperature and absorbed energy) has also been evaluated to see if they can be used as fire insulating materials. This work also studies the radiological activity of geopolymer materials. The replacement of FA with WTiO increases the bulk density due to its higher specific bulk density. The highest compressive strength values were obtained with a TiO waste content between 30 and 40% /. The compressive strength decreases at high temperatures, especially when more TiO waste is added. When the amount of TiO waste is increased, so is the plateau of evaporation, and this, in turn, increases the resistance to fire. Geopolymers containing FA and TiO waste do not present radiological problems, although, when the TiO waste is increased, the activity index of the geopolymer also rises.

摘要

本研究分析了二氧化钛废料(TiO废料)是否可作为具有良好耐火性能的地质聚合物的原料。制备了不同比例的样品,在地聚合物中用二氧化钛废料替代粉煤灰(0、20、30、40和100%/)。活化溶液的NaO/SiO摩尔比为0.98。评估了物理特性(堆积密度、含水量和吸水率)和机械特性(表面硬度和抗压强度)。此外,还评估了它们在高温下的热行为(耐火性、高温下的抗压强度和吸收能量),以确定它们是否可用作防火隔热材料。这项工作还研究了地质聚合物材料的放射性。用WTiO替代FA会因其较高的比堆积密度而增加堆积密度。TiO废料含量在30%至40%/之间时获得了最高抗压强度值。抗压强度在高温下会降低,尤其是添加更多TiO废料时。当TiO废料量增加时,蒸发平台也会增加,进而提高耐火性。含有FA和TiO废料的地质聚合物不存在放射性问题,不过,当TiO废料增加时,地质聚合物的活性指数也会上升。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f723/9737161/b66913d39966/materials-15-08493-g007.jpg

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