Zulkifly Khairunnisa, Cheng-Yong Heah, Yun-Ming Liew, Bayuaji Ridho, Abdullah Mohd Mustafa Al Bakri, Ahmad Shamsul Bin, Stachowiak Tomasz, Szmidla Janusz, Gondro Joanna, Jeż Bartłomiej, Khalid Mohd Suhaimi Bin, Garus Sebastian, Shee-Ween Ong, Wan-En Ooi, Hui-Teng Ng
Geopolymer and Green Technology, Center of Excellence (CEGeoGTech), Universiti Malaysia Perlis, Kangar 01000, Malaysia.
Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis, Perlis 01000, Malaysia.
Materials (Basel). 2021 Apr 15;14(8):1973. doi: 10.3390/ma14081973.
Thermal performance, combustibility, and fire propagation of fly ash-metakaolin (FA-MK) blended geopolymer with the addition of aluminum triphosphate, ATP (Al(HPO)), and monoaluminium phosphate, MAP (AlPO) were evaluated in this paper. To prepare the geopolymer mix, fly ash and metakaolin with a ratio of 1:1 were added with ATP and MAP in a range of 0-3% by weight. The fire/heat resistance was evaluated by comparing the residual compressive strengths after the elevated temperature exposure. Besides, combustibility and fire propagation tests were conducted to examine the thermal performance and the applicability of the geopolymers as passive fire protection. Experimental results revealed that the blended geopolymers with 1 wt.% of ATP and MAP exhibited higher compressive strength and denser geopolymer matrix than control geopolymers. The effect of ATP and MAP addition was more obvious in unheated geopolymer and little improvement was observed for geopolymer subjected to elevated temperature. ATP and MAP at 3 wt.% did not help in enhancing the elevated-temperature performance of blended geopolymers. Even so, all blended geopolymers, regardless of the addition of ATP and MAP, were regarded as the noncombustible materials with negligible (0-0.1) fire propagation index.
本文评估了添加磷酸铝(ATP,Al(HPO))和磷酸一铝(MAP,AlPO)的粉煤灰-偏高岭土(FA-MK)混合地质聚合物的热性能、燃烧性和火灾蔓延情况。为制备地质聚合物混合物,将比例为1:1的粉煤灰和偏高岭土与0至3%重量比的ATP和MAP混合。通过比较高温暴露后的残余抗压强度来评估耐火/耐热性。此外,进行了燃烧性和火灾蔓延测试,以检验地质聚合物作为被动防火材料的热性能和适用性。实验结果表明,添加1 wt.% ATP和MAP的混合地质聚合物比对照地质聚合物具有更高的抗压强度和更致密的地质聚合物基体。ATP和MAP添加的效果在未加热的地质聚合物中更明显,而对于经受高温的地质聚合物,观察到的改善较小。3 wt.%的ATP和MAP无助于提高混合地质聚合物的高温性能。即便如此,所有混合地质聚合物,无论是否添加ATP和MAP,都被视为具有可忽略不计(0 - 0.1)火灾蔓延指数的不燃材料。