Liao Wanneng, Zhang Chenxing, Qiang Hui, Song Weifei, Ren Hongwen
College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Materials (Basel). 2022 Dec 7;15(24):8724. doi: 10.3390/ma15248724.
Cu-Ni-Si alloy is the key raw material for the lead frame of large integrated circuits. The disordered grain orientation of alloy billet, high hardening rate, residual stress, and poor surface quality of cold working strips seriously affect its processability. In order to improve the cold-working properties of Cu-Ni-Si alloy, two kinds of C70250 copper alloy strips were produced through hot mold continuous casting (HMCC) and cold mold continuous casting (CMCC) technology. The effects of solidified microstructure on the cold-working deformation behavior, mechanical properties, and residual stress of the alloy were studied. The results show that C70250 copper alloys with columnar grain and equiaxed grain were prepared through HMCC and CMCC. After a 98% reduction in cold rolling, columnar grain strip surface quality was very good, and the elongation was still as high as 3.2%, which is 2.9 times that of equiaxed grain alloy. The residual stress of equiaxed grain strips reached 363 MPa, which is 2.7 times that of columnar grain strips. During the cold rolling process, equiaxed grain strips are prone to cause intersecting plane dislocations, stacking faults, shear bands, and grain breakage during large deformation cold rolling. The columnar grain strip causes parallel plane dislocations, stacking faults, and shearbands. Furthermore, the deformation structure was found to be uniform, and, ultimately, the alloy formed a fibrous structure. Therefore, the elongation and latter distortion of columnar grain strips improved after being put through large deformation cold rolling, which greatly reduced residual stress.
铜镍硅合金是大型集成电路引线框架的关键原材料。合金铸坯的晶粒取向无序、硬化速率高、残余应力大以及冷轧带材表面质量差严重影响其加工性能。为了改善铜镍硅合金的冷加工性能,通过热模连铸(HMCC)和冷模连铸(CMCC)技术制备了两种C70250铜合金带材。研究了凝固组织对合金冷加工变形行为、力学性能和残余应力的影响。结果表明,通过热模连铸和冷模连铸制备了具有柱状晶和等轴晶的C70250铜合金。冷轧压下率为98%后,柱状晶带材表面质量非常好,伸长率仍高达3.2%,是等轴晶合金的2.9倍。等轴晶带材的残余应力达到363MPa,是柱状晶带材的2.7倍。在冷轧过程中,等轴晶带材在大变形冷轧时容易产生相交面位错、层错、剪切带和晶粒破碎。柱状晶带材产生平行面位错、层错和剪切带。此外,发现变形组织均匀,最终合金形成纤维状组织。因此,柱状晶带材经过大变形冷轧后伸长率和后续变形得到改善,残余应力大大降低。