Sun Wenming, Li Shaolin, Song Kexing, Wang Qiangsong, Zhu Yingying
School of Material Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China.
Provincial and Ministerial Co-Construction Collaborative Innovation Center of Nonferrous New Materials and Advanced Processing Technology, Luoyang 471023, China.
Materials (Basel). 2023 Sep 30;16(19):6508. doi: 10.3390/ma16196508.
In this paper, a Cu-Ni-Cr alloy was prepared by adding a Ni-Cr intermediate alloy to copper. The effects of the cold rolling reduction rate on the microstructure and properties of the Cu-1.16Ni-0.36Cr alloy after thermo-mechanical treatment were studied. The results show that the tensile strength of the alloy increased while the electrical conductivity slightly decreased with an increase of the cold rolling reduction rate. At a rolling strain of 3.2, the tensile strength was 512.0 MPa and the conductivity was 45.5% IACS. At a rolling strain of 4.3, the strength further increased to 536.1 MPa and the conductivity decreased to 41.9% IACS. The grain size and dislocation density decreased with an increase of the reduction rate in the thermo-mechanical treatment. However, when the rolling strain reached 4.3, the recrystallization degree of the alloy increased due to an accumulation of the dislocation density and deformation energy, resulting in a slight increase in the grain size and a decrease in the dislocation density. The texture strength of the brass increased due to the induced shear band, with an increase of the cold rolling reduction rate. The reduction rate promoted a uniform distribution of nano-scale Cr precipitates and further enhanced the strength via precipitation strengthening.
在本文中,通过向铜中添加镍 - 铬中间合金制备了一种铜 - 镍 - 铬合金。研究了冷轧压下率对热机械处理后的Cu-1.16Ni-0.36Cr合金组织和性能的影响。结果表明,随着冷轧压下率的增加,合金的抗拉强度增加,而电导率略有下降。在轧制应变为3.2时,抗拉强度为512.0MPa,电导率为45.5%IACS。在轧制应变为4.3时,强度进一步增加到536.1MPa,电导率下降到41.9%IACS。在热机械处理中,随着压下率的增加,晶粒尺寸和位错密度减小。然而,当轧制应变达到4.3时,由于位错密度和变形能的积累,合金的再结晶程度增加,导致晶粒尺寸略有增加,位错密度降低。由于诱导剪切带的作用,随着冷轧压下率的增加,黄铜的织构强度增加。压下率促进了纳米级Cr析出相的均匀分布,并通过析出强化进一步提高了强度。