配体促进的通过 borrowing-hydrogen 途径的酮的[Pd]催化α-烷基化反应。
Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach.
机构信息
Centre for Analysis and Synthesis, Department of Chemistry, Lund University, P. O. Box 124, 221 00, Lund, Sweden.
Perstorp AB, Perstorp Industrial Park, 284 80, Perstorp, Sweden.
出版信息
ChemistryOpen. 2023 Jan;12(1):e202200245. doi: 10.1002/open.202200245.
Abstract
A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.
摘要
一类新型钯配合物已被制备并通过双齿 2-羟基吡啶基配体进行了充分的表征。这些新配合物在醇与酮的烷基化反应中通过金属-配体协同借氢（BH）过程的应用得到了证明。
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