Department of Chemical Sciences, Indian Institute of Science Education and Research Mohali, Punjab, 140306, India.
Chem Commun (Camb). 2023 Jan 24;59(8):1042-1045. doi: 10.1039/d2cc06225a.
Two multichromophoric FRET macrocycles M1 [1+1] and M2 [2+2] with red emission ( ∼ 721 nm) composed of perylenediimide (PDI) as the energy donor and aza-BODIPY (ABDP) as the energy acceptor were synthesized by click reaction in a metal-free fashion. M1 and M2 exhibited distinct reversible ratiometric temperature responsive emission with temperature sensitivities of 0.09-0.14% °C and owing to the redox active chromophores, they showed solution phase redox responsive reversible colour changes.
两个多色荧光共振能量转移（FRET）大环 M1 [1+1] 和 M2 [2+2] 具有红色发射（∼721nm），由作为能量供体的苝二酰亚胺（PDI）和作为能量受体的氮杂 BODIPY（ABDP）组成，通过点击反应在无金属条件下合成。M1 和 M2 表现出明显的可逆比率型温度响应发射，温度灵敏度为 0.09-0.14% °C，并且由于氧化还原活性发色团，它们表现出溶液相氧化还原响应的可逆颜色变化。
