Xue Shanshan, Li Pengfei, Sun Lu, An Li, Qu Dan, Wang Xiayan, Sun Zaicheng
Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry, Beijing University of Technology, 100 Pingleyuan, Beijing, 100124, P. R. China.
Small. 2023 Aug;19(31):e2206180. doi: 10.1002/smll.202206180. Epub 2023 Jan 17.
Fluorescent carbon dots are a novel type of nanomaterial. Due to their excellent optical properties, they have extensive application prospects in many fields. Studying the formation process and fluorescence mechanism of CDs will assist scientists in understanding the synthesis of CDs and guide more profound applications. Due to their conjugated structures, aromatic compounds have been continuously used to synthesize CDs, with emissions ranging from blue to NIR. There is a lack of a systematic summary of the formation process and fluorescence mechanism of aromatic precursors to form CDs. In this review, the formation process of CDs is first categorized into three main classes according to the precursor types of aromatic compounds: amines, phenols, and polycyclics. And then, the fluorescence mechanism of CDs synthesized from aromatic compounds is summarized. The challenges and prospects are proposed in the last section.
荧光碳点是一种新型纳米材料。由于其优异的光学性能,它们在许多领域具有广泛的应用前景。研究碳点的形成过程和荧光机制将有助于科学家理解碳点的合成,并指导更深入的应用。由于其共轭结构,芳香族化合物已被不断用于合成碳点,其发射范围从蓝色到近红外。目前缺乏对芳香族前体形成碳点的形成过程和荧光机制的系统总结。在这篇综述中,根据芳香族化合物的前体类型,碳点的形成过程首先被分为三大类:胺类、酚类和多环芳烃类。然后,总结了由芳香族化合物合成的碳点的荧光机制。最后一部分提出了挑战和前景。