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基于木质纤维素生物质的碳点:合成工艺、性质及应用

Lignocellulosic Biomass-Based Carbon Dots: Synthesis Processes, Properties, and Applications.

作者信息

Gan Jian, Chen Lizhen, Chen Zhijun, Zhang Jilei, Yu Wenji, Huang Caoxing, Wu Yan, Zhang Kai

机构信息

Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing, 210037, China.

Sustainable Materials and Chemistry, Department of Wood Technology and Wood-Based Composites, University of Göttingen, 37077, Göttingen, Germany.

出版信息

Small. 2023 Nov;19(48):e2304066. doi: 10.1002/smll.202304066. Epub 2023 Aug 3.

Abstract

Carbon dots (CDs), a new type of carbon-based fluorescent nanomaterial, have attracted widespread attention because of their numerous excellent properties. Lignocellulosic biomass is the most abundant renewable natural resource and possesses broad potential to manufacture different composite and smart materials. Numerous studies have explored the potential of using the components (such as cellulose, hemicellulose, and lignin) in lignocellulosic biomass to produce CDs. There are few papers systemically aiming in the review of the state-of-the-art works related to lignocellulosic biomass-derived CDs. In this review, the significant advances in synthesis processes, formation mechanisms, structural characteristics, optical properties, and applications of lignocellulosic biomass-based CDs such as cellulose-based CDs, hemicellulose-based CDs and lignin-based CDs in latest research are reviewed. In addition, future research directions on the improvement of the synthesis technology of CDs using lignocellulosic biomass as raw materials to enhance the properties of CDs are proposed. This review will serve as a road map for scientists engaged in research and exploring more applications of CDs in different science fields to achieve the highest material performance goals of CDs.

摘要

碳点(CDs)是一种新型的碳基荧光纳米材料,因其众多优异性能而受到广泛关注。木质纤维素生物质是最丰富的可再生自然资源,具有制造不同复合材料和智能材料的广阔潜力。众多研究探索了利用木质纤维素生物质中的成分(如纤维素、半纤维素和木质素)来制备碳点的潜力。很少有论文系统地对与木质纤维素生物质衍生碳点相关的最新研究成果进行综述。在本综述中,对木质纤维素生物质基碳点(如纤维素基碳点、半纤维素基碳点和木质素基碳点)在最新研究中的合成工艺、形成机制、结构特征、光学性质及应用方面的重大进展进行了综述。此外,还提出了以木质纤维素生物质为原料改进碳点合成技术以提升其性能的未来研究方向。本综述将为从事碳点研究并探索其在不同科学领域更多应用以实现碳点最高材料性能目标的科学家们提供路线图。

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