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处于经典与量子领域边缘的物质聚集低维纳米结构。

Matter-Aggregating Low-Dimensional Nanostructures at the Edge of the Classical vs. Quantum Realm.

作者信息

Gadomski Adam, Kruszewska Natalia

机构信息

Institute of Mathematics and Physics (Group of Modeling of Physicochemical Processes), Faculty of Chemical Technology and Engineering, Bydgoszcz University of Science and Technology, Kaliskiego 7 Street, 85-796 Bydgoszcz, Poland.

出版信息

Entropy (Basel). 2022 Dec 20;25(1):1. doi: 10.3390/e25010001.

Abstract

This commentary tackles the subtle at-the-edge problem of passing locally by a mesoscopic matter-aggregating system from a classical stochastic to a quantum stochastic description. A -dimensional entropy-productive aggregation of the matter is taken as the starting point. Then, a dimensional reduction towards a one-dimensional quantum-wire type matter-aggregation system is proposed, resulting in postponing surface-tension conditions for the effectively = 1-dimensional quantum-wire type or nanorod-like cluster/polycrystal, which is qualitatively consistent with a physical-metallurgical (high-temperature) Louat's grain growth model. A certain recuperative interplay based on maneuvering between subtle temperature rises applied to the system under study while maintaining its quantum character (the so-called Nelson's quantum-stochastic procedure) within the limits of a vanishing Planck's constant, involved in the diffusivity measure of the aggregation, is discussed. Certain applications towards the formation of = 1-dimensional semiconductors and other nanostructures (possibly using soft materials or (bio)polymeric materials such as nanofibers) are envisioned. As a special example, one may propose a nanotechnological process which is termed the Van der Waals heteroepitaxy. The process itself contains the main quantum vs. classical crossover due to the involvement of weak repulsion (quantum) vs. attraction (treated classically) interactions, which are represented by a Lennard-Jones-type potential.

摘要

本评论探讨了一个微妙的边缘问题,即介观物质聚集系统如何从经典随机描述过渡到量子随机描述。以物质的一维熵产生聚集为出发点。然后,提出了向一维量子线型物质聚集系统的降维,从而推迟了有效一维量子线型或纳米棒状团簇/多晶体的表面张力条件,这在定性上与物理冶金(高温)卢阿特晶粒生长模型一致。讨论了一种基于在对所研究系统施加微妙温度升高之间进行操纵的恢复性相互作用,同时在普朗克常数消失的极限内保持其量子特性(所谓的尼尔森量子随机过程),该过程涉及聚集的扩散率测量。设想了在形成一维半导体和其他纳米结构(可能使用软材料或(生物)聚合材料如纳米纤维)方面的某些应用。作为一个特殊例子,可以提出一种称为范德华异质外延的纳米技术过程。由于弱排斥(量子)与吸引(经典处理)相互作用的参与,该过程本身包含了主要的量子与经典交叉,这些相互作用由 Lennard-Jones 型势表示。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0c2d/9857855/46b94241bee6/entropy-25-00001-g001.jpg

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