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高压机器中的混合压力对自由发泡硬质聚氨酯泡沫塑料形态和物理性能的影响——案例研究

The Effect of Mixing Pressure in a High-Pressure Machine on Morphological and Physical Properties of Free-Rising Rigid Polyurethane Foams-A Case Study.

作者信息

Węgrzyk Grzegorz, Grzęda Dominik, Ryszkowska Joanna

机构信息

Faculty of Materials Science and Engineering, Warsaw University of Technology, ul. Wołoska 141, 02-507 Warsaw, Poland.

出版信息

Materials (Basel). 2023 Jan 16;16(2):857. doi: 10.3390/ma16020857.

Abstract

This article presents the results of testing foam blocks made with a high-pressure foaming machine under industrial conditions. Foam blocks were made at pressures in the range of 110-170 bar with substrate temperatures allowed by machine suppliers. The foaming process parameters of each block were evaluated. The structure of the foams in the outer and central parts of the blocks was characterized using FTIR spectroscopic analysis and microscopic observations using SEM. The changes in apparent density, strength properties and brittleness of the foams were evaluated. The properties of the blocks made at different mixing pressures varied depending on the pressure at which the substrates were mixed and the location in the block. The biggest differences that were observed were the friability of the foams taken from different locations in the blocks by up to about 30%; the apparent density differed by about 8% and the compressive strength by about 5%.

摘要

本文介绍了在工业条件下用高压发泡机制备泡沫块的测试结果。泡沫块在110 - 170巴的压力下制备,底物温度由机器供应商提供。评估了每个泡沫块的发泡工艺参数。利用傅里叶变换红外光谱(FTIR)分析和扫描电子显微镜(SEM)微观观察对泡沫块外层和中心部分的泡沫结构进行了表征。评估了泡沫表观密度、强度性能和脆性的变化。在不同混合压力下制备的泡沫块的性能因底物混合时的压力以及在泡沫块中的位置而异。观察到的最大差异是,从泡沫块不同位置取出的泡沫的易碎性相差高达约30%;表观密度相差约8%,抗压强度相差约5%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff69/9866240/94cd922263e5/materials-16-00857-g001.jpg

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