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用于超滤过程中高过滤和抗污染性能的酸功能化碳纳米管共混纳米复合中空纤维膜的制备与研究

Fabrication and Investigation of Acid Functionalized CNT Blended Nanocomposite Hollow Fiber Membrane for High Filtration and Antifouling Performance in Ultrafiltration Process.

作者信息

Yang Eunmok, Park Shinyun, Kim Yeji, Yanar Numan, Choi Heechul

机构信息

School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea.

Department of Civil and Environmental Engineering, Colorado State University, Fort Collins, CO 80523, USA.

出版信息

Membranes (Basel). 2023 Jan 5;13(1):70. doi: 10.3390/membranes13010070.

Abstract

In this study, we fabricated a nanocomposite polyethersulfone (PES) HF membrane by blending acid functionalized carbon nanotubes (FCNT) to address the issue of reduced membrane life, increased energy consumption, and operating costs due to low permeability and membrane fouling in the ultrafiltration process. Additionally, we investigated the effect of FCNT blending on the membrane in terms of the physicochemical properties of the membrane and the filtration and antifouling performance. The FCNT/PES nanocomposite HF membrane exhibited increased water permeance from 110.1 to 194.3 LMH/bar without sacrificing rejection performance and increased the flux recovery ratio from 89.0 to 95.4%, compared to a pristine PES HF membrane. This study successfully developed a high filtration and antifouling polymer-based HF membrane by blending FCNT. Furthermore, it was validated that blending FCNT into the membrane enhances the filtration and antifouling performance in the ultrafiltration process.

摘要

在本研究中,我们通过将酸功能化碳纳米管(FCNT)与聚醚砜(PES)共混制备了一种纳米复合中空纤维(HF)膜,以解决超滤过程中由于低渗透性和膜污染导致的膜寿命缩短、能耗增加及运行成本上升的问题。此外,我们从膜的物理化学性质以及过滤和抗污染性能方面研究了FCNT共混对膜的影响。与原始的PES HF膜相比,FCNT/PES纳米复合HF膜的水渗透通量从110.1增加到194.3 LMH/bar,同时截留性能并未降低,通量恢复率从89.0%提高到95.4%。本研究通过共混FCNT成功开发出了一种具有高过滤和抗污染性能的聚合物基HF膜。此外,还证实了将FCNT共混到膜中可增强超滤过程中的过滤和抗污染性能。

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