外电场对互变异构分子平衡性质的影响和作用。
Effects and Influence of External Electric Fields on the Equilibrium Properties of Tautomeric Molecules.
机构信息
Institute of Electronics, Bulgarian Academy of Sciences, 1784 Sofia, Bulgaria.
出版信息
Molecules. 2023 Jan 10;28(2):695. doi: 10.3390/molecules28020695.
In this review, we have attempted to briefly summarize the influence of an external electric field on an assembly of tautomeric molecules and to what experimentally observable effects this interaction can lead to. We have focused more extensively on the influence of an oriented external electric field (OEEF) on excited-state intramolecular proton transfer (ESIPT) from the studies available to date. The possibilities provided by OEEF for regulating several processes and studying physicochemical processes in tautomers have turned this direction into an attractive area of research due to its numerous applications.
在这篇综述中，我们试图简要总结外电场对互变异构分子组装体的影响，以及这种相互作用可能导致哪些可观察到的实验效应。我们更广泛地关注了迄今为止可用的研究中，定向外电场（OEEF）对激发态分子内质子转移（ESIPT）的影响。OEEF 为调节几个过程提供了可能性，并为互变异构体中的物理化学过程研究提供了可能性，由于其众多的应用，这一方向已成为一个有吸引力的研究领域。
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