Reid Jolene P
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, V6T 1Z1, Canada.
Commun Chem. 2021 Dec 9;4(1):171. doi: 10.1038/s42004-021-00614-y.
The transfer of chiral information from optically pure reaction components to products can generate enantiomerically-enriched molecules, but the control of stereochemistry often proves challenging. Here, the author highlights how our fundamental understanding of stereocontrol has evolved and discusses possible approaches for the rational development of enantioselective catalysts.
将手性信息从光学纯的反应组分传递到产物中能够生成对映体富集的分子，但立体化学的控制往往颇具挑战性。在此，作者着重介绍了我们对立体控制的基本理解是如何演变的，并讨论了合理开发对映选择性催化剂的可能方法。
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